1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

Base Information

Chemical Name:1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide
CAS No.:706791-39-1
Molecular Formula:C₂₇H₂₆FeNO₂P
Molecular Weight:483.33
Hs Code.:

Synonyms:1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

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Chemical Property of 1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

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Technology Process of 1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

There total 1 articles about 1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 110-91-8,99108-56-2
morpholine

: 173346-69-5
1′-(diphenylphosphino)ferrocene-1-carboxylic acid

: 706791-39-1
1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

Guidance literature:: With 1-hydroxybenzotriazole; N-(3-(dimethylamino)propyl)-N'-ethylcarbodiimide; In dichloromethane; (Ar); exclusion of direct sunlight; 1-hydroxybenzotriazole and N-(3-(dimethylamino)propyl)-N'-ethylcarbodiimide were added to ice-cold soln. of Fe complex in CH2Cl2; mixt. stirred at 0°C for 1 h; morpholine added; stirred at room temp. overnight; extd. (HCl, satd. aq. NaHCO3, H2O); org. phase dried (MgSO4); evapd.; chromd. (silica gel, CH2Cl2/methanol, 10/1); evapd. (60°C/0.3 Torr);
DOI:10.1021/om040007f

Reference yield: 19.0%

: 706791-39-1
1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

: 199620-14-9,13007-92-6
chromium⁽⁰⁾ hexacarbonyl

: [(4-morpholinyl)(1'-(diphenylphosphino-κP)ferrocenyl)methylidene-κC1]tetracarbonylchromium(0)

: 706791-43-7
[1'-(diphenylphosphino-κP)ferrocenecarboxylic acid morpholide]pentacarbonylchromium(0)

Guidance literature:: With Na; naphthalene; Me₃SiCl; In tetrahydrofuran; (Ar); exclusion of sunlight; Na/C10H8/THF stirred at room temp.; soln. added to Cr compd./THF at -78°C; stirred at 0°C for 0.5 h; Fe compd./THF added at -78°C; stirred at 0°C for 0.5 h; Me3SiCl added at -78°C; stirred; warmed to room temp. for 1 h with stirring; mixed with alumina; solvent removed (vac.); residue dried (vac.); mixed with light petroleum; chromd. (alumina, hexane/CH2Cl2 (1/1), CH2Cl2); elem. anal.;
DOI:10.1021/om040007f