1′-(diphenylphosphino)ferrocene-1-carboxylic acid

Base Information

Chemical Name:1′-(diphenylphosphino)ferrocene-1-carboxylic acid
CAS No.:173346-69-5
Molecular Formula:C₂₃H₁₉FeO₂P
Molecular Weight:414.223
Hs Code.:

Synonyms:1′-(diphenylphosphino)ferrocene-1-carboxylic acid

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Chemical Property of 1′-(diphenylphosphino)ferrocene-1-carboxylic acid

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Technology Process of 1′-(diphenylphosphino)ferrocene-1-carboxylic acid

There total 1 articles about 1′-(diphenylphosphino)ferrocene-1-carboxylic acid which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 52.0%

: 252366-56-6
rac-1',2-dibromoferrocene-1-carboxylic acid

: 1079-66-9,74391-44-9
chloro-diphenylphosphine

: 173346-69-5
1′-(diphenylphosphino)ferrocene-1-carboxylic acid

: 297176-74-0,847675-62-1,677722-99-5
(Sp)-2-(diphenylphosphino)ferrocenecarboxylic acid

: 1186221-40-8,1186221-45-3,1186221-46-4
1',2-bis(diphenylphosphino)ferrocene-1-carboxylic acid

Guidance literature:: With CH₃(CH₂)3Li; In tetrahydrofuran; hexane; (Ar, exclusion of light); dropwise addn. of hexane soln. of C4H9Li to soln. of iron compd. in C4H8O under cooling (-78°C), stirring (-78°C, 2 h), treatment with ClP(C6H5)2, stirring (-78°C, 30 min), stirring (room temp., 18 h); addn. 5 % aq. KOH, evapn. under vacuum, extn. ((C2H5)2O), addn. concd. H3PO4 to pH~2, isolation of ppt., addn. C4H8O, phase sepn., extn.(C4H8O), washing with brine, drying (MgSO4), evapn., chromy. (silica ge l, CH2Cl2/CH3OH (10:1)), evapn.;
DOI:10.1039/b901262a

Reference yield: 99.0%

: 110-91-8,99108-56-2
morpholine

: 173346-69-5
1′-(diphenylphosphino)ferrocene-1-carboxylic acid

: 706791-39-1
1'-(diphenylphosphino)ferrocenecarboxylic acid morpholide

Guidance literature:: With 1-hydroxybenzotriazole; N-(3-(dimethylamino)propyl)-N'-ethylcarbodiimide; In dichloromethane; (Ar); exclusion of direct sunlight; 1-hydroxybenzotriazole and N-(3-(dimethylamino)propyl)-N'-ethylcarbodiimide were added to ice-cold soln. of Fe complex in CH2Cl2; mixt. stirred at 0°C for 1 h; morpholine added; stirred at room temp. overnight; extd. (HCl, satd. aq. NaHCO3, H2O); org. phase dried (MgSO4); evapd.; chromd. (silica gel, CH2Cl2/methanol, 10/1); evapd. (60°C/0.3 Torr);
DOI:10.1021/om040007f

Reference yield: 98.0%

: 173346-69-5
1′-(diphenylphosphino)ferrocene-1-carboxylic acid

: 5680-79-5,883886-67-7
glycine ethyl ester hydrochloride

: 1160484-10-5
1-diphenylphosphino-1'-(N-[(methoxycarbonyl)methyl]carbamoyl)ferrocene

Guidance literature:: With (CH₃)2NCH₂CH₂CH₂NCNCH₂CH₃; 1-hydroxybenzotriazole; N(CH₂CH₃)3; In dichloromethane; (Ar, dark); addn. of diimide deriv. to CH2Cl2 soln. of ferrocene deriv. and benzotriazole at 0°C, stirring at 0°C for 30 min, addn. of glycine deriv. and triethylamine in CH2Cl2, stirring overnight at room temp.; washing with aq. citric acid, satd. aq. NaHCO3 and brine, drying over MgSO4, evapn., chromy. (silica gel, CH2Cl2/methanol (10:1)), evapn., elem.anal.;
DOI:10.1021/om900209j