3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

Base Information

Chemical Name:3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime
CAS No.:368447-70-5
Molecular Formula:C₁₆H₁₇NO₂S
Molecular Weight:287.382
Hs Code.:

Synonyms:3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

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Chemical Property of 3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

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Technology Process of 3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

There total 23 articles about 3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 73771-35-4
3-(methylsulfanyl)benzaldehyde

: 368447-63-6
(S)-2-(aminooxy)-2-phenylethanediol

: 368447-70-5
3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

Guidance literature:: With toluene-4-sulfonic acid; In toluene; for 0.5h; Heating;
DOI:10.1021/jo049517+

Reference yield:

: 757195-16-7
2-{[(2R)-2-(methoxymethoxy)-2-phenylethyl]oxy}-1H-isoindole-1,3(2H)-dione

: 368447-70-5
3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

Guidance literature:: Multi-step reaction with 7 steps

1.1: conc. HCl / methanol / 0.5 h / 20 °C

1.2: 99 percent / hydrazine hydrate / ethanol / 1 h / Heating

2.1: 99 percent / TsOH / toluene / 0.5 h / Heating

3.1: 60 percent / toluene; diethyl ether / 0.42 h / -20 °C

4.1: Mo(CO)6 / acetonitrile; H₂O / 1 h / 85 °C

5.1: 81 percent / triphenylphosphine; diethyl azodicarboxylate / tetrahydrofuran / 48 h / 20 °C

6.1: 99 percent / hydrazine hydrate / ethanol / 1 h / Heating

7.1: 99 percent / TsOH / toluene / 0.5 h / Heating

With hydrogenchloride; hexacarbonyl molybdenum; toluene-4-sulfonic acid; hydrazine hydrate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; diethyl ether; ethanol; water; toluene; acetonitrile; 5.1: Mitsunobu reaction;
DOI:10.1021/jo049517+

Reference yield:

: 20698-91-3
(R)-methyl mandelate

: 368447-70-5
3-(methylsulfanyl)benzaldehyde (E)-O-[(1S)-2-hydroxy-1-phenylethyl]oxime

Guidance literature:: Multi-step reaction with 4 steps

1: 97 percent / NaBH₄ / methanol / 0.5 h / 20 °C

2: 81 percent / triphenylphosphine; diethyl azodicarboxylate / tetrahydrofuran / 48 h / 20 °C

3: 99 percent / hydrazine hydrate / ethanol / 1 h / Heating

4: 99 percent / TsOH / toluene / 0.5 h / Heating

With sodium tetrahydroborate; toluene-4-sulfonic acid; hydrazine hydrate; triphenylphosphine; diethylazodicarboxylate; In tetrahydrofuran; methanol; ethanol; toluene; 2: Mitsunobu reaction;
DOI:10.1021/jo049517+