4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

Base Information

Chemical Name:4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester
CAS No.:79036-63-8
Molecular Formula:C₂₆H₃₀O₈
Molecular Weight:470.519
Hs Code.:

Synonyms:4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

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Chemical Property of 4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

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Technology Process of 4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

There total 5 articles about 4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 87.0%

: 79036-65-0
3-Oxo-2-(3-oxo-butyl)-2-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-succinic acid diethyl ester

: 79036-63-8
4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

Guidance literature:: With pyrrolidine; acetic acid; In benzene; for 5h; Heating;
DOI:10.1016/S0040-4039(01)90406-X

Reference yield:

: 79036-69-4
5,8-dimethoxy-7-methyl-3,4-dihydro-2H-naphthalen-1-one

: 79036-63-8
4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

Guidance literature:: Multi-step reaction with 5 steps

1: DDQ / methanol, reflux, 24 h

2: 1.) NaH 2.) hydrogen / 5percent Pd/C / 1.) benzene, room temp., 4 h 2.) EtOH, room temp.

3: 68 percent / NaH / benzene / 20 h / 55 °C

4: 80 percent / Et₃N / ethanol; benzene / 20 h / Heating

5: 87 percent / Pyrrolidine / AcOH / benzene / 5 h / Heating

With pyrrolidine; hydrogen; sodium hydride; 2,3-dicyano-5,6-dichloro-p-benzoquinone; palladium on activated charcoal; acetic acid; triethylamine; In ethanol; benzene;
DOI:10.1016/S0040-4039(01)90406-X

Reference yield:

: 79036-67-2
3-(1,4,8-Trimethoxy-naphthalen-2-yl)-propionic acid ethyl ester

: 79036-63-8
4-Oxo-1-(1,4,8-trimethoxy-naphthalen-2-ylmethyl)-cyclohex-2-ene-1,2-dicarboxylic acid diethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 68 percent / NaH / benzene / 20 h / 55 °C

2: 80 percent / Et₃N / ethanol; benzene / 20 h / Heating

3: 87 percent / Pyrrolidine / AcOH / benzene / 5 h / Heating

With pyrrolidine; sodium hydride; acetic acid; triethylamine; In ethanol; benzene;
DOI:10.1016/S0040-4039(01)90406-X