Technology Process of (Z)-15-benzenesulfonyl-6-pentadecene
There total 4 articles about (Z)-15-benzenesulfonyl-6-pentadecene which
guide to synthetic route it.
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synthetic route:
- Guidance literature:
-
With
potassium hexamethylsilazane;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; toluene;
at -78 - 20 ℃;
DOI:10.1271/bbb.69.1620
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: butyllithium / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 0.5 h / -78 °C
1.2: 97 percent / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 8 h / -78 - 20 °C
2.1: 100 percent / oxalyl chloride; DMSO; Et3N / CH2Cl2 / -78 - 20 °C
3.1: 94 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene; hexamethylphosphoric acid triamide / -78 - 20 °C
With
n-butyllithium; oxalyl dichloride; potassium hexamethylsilazane; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; toluene;
2.1: Swern oxidation / 3.1: Wittig olefination;
DOI:10.1271/bbb.69.1620
- Guidance literature:
-
Multi-step reaction with 3 steps
1.1: butyllithium / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 0.5 h / -78 °C
1.2: 97 percent / hexane; tetrahydrofuran; hexamethylphosphoric acid triamide / 8 h / -78 - 20 °C
2.1: 100 percent / oxalyl chloride; DMSO; Et3N / CH2Cl2 / -78 - 20 °C
3.1: 94 percent / potassium hexamethyldisilazide / tetrahydrofuran; toluene; hexamethylphosphoric acid triamide / -78 - 20 °C
With
n-butyllithium; oxalyl dichloride; potassium hexamethylsilazane; dimethyl sulfoxide; triethylamine;
In
tetrahydrofuran; N,N,N,N,N,N-hexamethylphosphoric triamide; hexane; dichloromethane; toluene;
2.1: Swern oxidation / 3.1: Wittig olefination;
DOI:10.1271/bbb.69.1620
