Phenyl-1 trimethyl-1,3,4 silole

Base Information

• Chemical Name: Phenyl-1 trimethyl-1,3,4 silole
• CAS No.: 98749-91-8
• Molecular Formula: C₁₃H₁₆Si
• Molecular Weight: 200.356
• Mol file: 98749-91-8.mol

Synonyms:Phenyl-1 trimethyl-1,3,4 silole

Chemical Property of Phenyl-1 trimethyl-1,3,4 silole

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of Phenyl-1 trimethyl-1,3,4 silole

There total 1 articles about Phenyl-1 trimethyl-1,3,4 silole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 9.0%

tetramethyl-1,1,3,4 silole (82763-95-9) + phenyllithium (591-51-5) → 1-phenyl-1,3-dimethyl-4-methylene-silacyclopent-2-ene (98749-92-9) + Phenyl-1 trimethyl-1,3,4 silole (98749-91-8)

Guidance literature:

In diethyl ether; benzene; at -70 - 25 ℃; for 2h; Yield given. Title compound not separated from byproducts;

DOI:10.1016/S0040-4039(00)94880-9

Reference yield: 75.0%

[(1,5-cyclooctadiene)Rh(PPh3)2]PF6 (35238-97-2) + Phenyl-1 trimethyl-1,3,4 silole (98749-91-8) → {Rh(η4-Me2C4H2SiMePh)(PPh3)2}(PF6) (129176-24-5)

Guidance literature:

With hydrogen; In tetrahydrofuran; byproducts: C8H8; Ar atmosphere; stirring soln. of Rh-compd. in THF under a stream of H2, addn. of soln. of org. compd. in THF; filtn., further product on addn. of Et2O, recrystn. (-20°C, CH2Cl2/pentane (1/1)); elem. anal.;

Reference yield: 70.0%

[{1,2:5,6-η-(1,5-cyclooctadiene)}-bis(triphenylphosphine)]rhodium tetrafluoroborate (32762-45-1) + Phenyl-1 trimethyl-1,3,4 silole (98749-91-8) → {Rh(η4-Me2C4H2SiMePh)(PPh3)2}(BF4) (129176-24-5)

Guidance literature:

With hydrogen; In tetrahydrofuran; byproducts: C8H8; Ar atmosphere; stirring soln. of Rh-compd. in THF under stream of H2, addn. of org. compd. in THF; filtn., further product on addn. of Et2O, recrystn. (-20°C, CH2Cl2/pentane (1/1));

upstream raw materials:

tetramethyl-1,1,3,4 silole

phenyllithium

Downstream raw materials:

{Rh(η4-Me2C4H2SiMePh)(PPh3)2}(PF6)

{Rh(η4-Me2C4H2SiMePh)(PPh3)2}(BF4)

{Rh(η4-Me2C4H2SiMePh)(PPh3)2}(SbF6)

(C₄H₂(CH₃)2Si(CH₃)C₆H₅)Fe(CO)3