(bis(diphenylphosphino)ethane)(oxalato)palladium(II)

Base Information

• Chemical Name: (bis(diphenylphosphino)ethane)(oxalato)palladium(II)
• CAS No.: 94929-12-1
• Molecular Formula: C₂₈H₂₄O₄P₂Pd
• Molecular Weight: 592.864
• Mol file: 94929-12-1.mol

Synonyms:(bis(diphenylphosphino)ethane)(oxalato)palladium(II)

Chemical Property of (bis(diphenylphosphino)ethane)(oxalato)palladium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (bis(diphenylphosphino)ethane)(oxalato)palladium(II)

There total 2 articles about (bis(diphenylphosphino)ethane)(oxalato)palladium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

(1,2-bis(diphenylphosphino)ethane)palladium(II) chloride (19978-61-1) + silver oxalate (15843-43-3,31038-77-4) → (bis(diphenylphosphino)ethane)(oxalato)palladium(II) (94929-12-1)

Guidance literature:

In methanol; excess Ag2C2O4 added to a suspn. of the Pd-complex in methanol, stirredand refluxed for 12 h; filtered in subdued light, solvent removed under reduced pressure, recrystd. twice from hot MeOH/Et2O, dried under vacuum, elem. anal.;

DOI:10.1021/om00123a006

Reference yield: 60.0%

dichloro(cycloocta-1,5-diene)palladium (II) (12107-56-1) → [(diphenylphosphinoethane)Pd(C2O4)] (94929-12-1)

Guidance literature:

With 1,2-bis-(diphenylphosphino)ethane; In dichloromethane; byproducts: AgCl; Ar, dppe in CH2Cl2 added dropwise to Pd-compound in soln., Ag2C2O4 introduced, stirred in the dark for several days; filtered, concd., ether added, filtered, washed (ether), dried by suction,; elem. anal.;

DOI:10.1016/0022-328X(92)83310-E

Reference yield: 75.0%

ammonium hexafluorophosphate + (bis(diphenylphosphino)ethane)(oxalato)palladium(II) (94929-12-1) + Allyl acetate (591-87-7) → (η3-allyl)(bis(diphenylphosphino)ethane)palladium hexafluorophosphate (41449-73-4)

Guidance literature:

In ethanol; acetonitrile; byproducts: CO2; Irradiation (UV/VIS); allyl acetate added to the Pd-complex suspd. in CH3CN, irradiated for 30 min (.ltorsim. 313 nm), volume reduced, soln. of NH4PF6 in EtOH added; cooled to -20°C, pptd., filtrate removed, washed twice with EtOHand twice with Et2O, recrystd. from CH2Cl2/Et2O, dried under vacuum, elem. anal.;

DOI:10.1021/om00123a006

upstream raw materials:

(1,2-bis(diphenylphosphino)ethane)palladium(II) chloride

silver oxalate

dichloro(cycloocta-1,5-diene)palladium (II)

Downstream raw materials:

{Pd(1,2-bis(diphenylphosphanyl)ethane)(C₂H₄)}

(η3-allyl)(bis(diphenylphosphino)ethane)palladium hexafluorophosphate

(1,2-bis(diphenylphosphino)ethane)palladium(II) chloride

Pd(C₂F₄)((C₆H₅)2PCH₂CH₂P(C₆H₅)2)