(1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

Base Information

Chemical Name:(1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan
CAS No.:168417-02-5
Molecular Formula:C₂₁H₃₀O₄S
Molecular Weight:378.533
Hs Code.:

Synonyms:(1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

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Chemical Property of (1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

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Technology Process of (1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

There total 6 articles about (1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 94.0%

: 168417-01-4
(1R,3S,3aS,4R,4aS,8aR,9aS)-1-Methoxy-3-methyl-4-phenylsulfanylmethyl-dodecahydro-naphtho[2,3-c]furan

: 168417-02-5
(1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

Guidance literature:: With sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00141a036

Reference yield:

: 168416-98-6
(3S,3aR,4R,4aS,8aR,9aS)-4-Hydroxymethyl-3-methyl-decahydro-naphtho[2,3-c]furan-1-one

: 168417-02-5
(1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

Guidance literature:: Multi-step reaction with 5 steps

1: pyridine

2: KO-t-Bu, DMSO

3: i-BuAlH / diethyl ether; hexane

4: BF₃*Et₂O / CH₂Cl₂

5: 94 percent / m-CPBA, NaHCO₃ / CH₂Cl₂

With pyridine; boron trifluoride diethyl etherate; potassium tert-butylate; diisobutylaluminium hydride; sodium hydrogencarbonate; dimethyl sulfoxide; 3-chloro-benzenecarboperoxoic acid; In diethyl ether; hexane; dichloromethane;
DOI:10.1021/ja00141a036

Reference yield:

: 192133-56-5
(3S,3aS,4R,4aS,8aR,9aS)-3-Methyl-4-phenylsulfanylmethyl-dodecahydro-naphtho[2,3-c]furan-1-ol

: 168417-02-5
(1R,3S,3aS,4R,4aS,8aR,9aS)-4-Benzenesulfonylmethyl-1-methoxy-3-methyl-dodecahydro-naphtho[2,3-c]furan

Guidance literature:: Multi-step reaction with 2 steps

1: BF₃*Et₂O / CH₂Cl₂

2: 94 percent / m-CPBA, NaHCO₃ / CH₂Cl₂

With boron trifluoride diethyl etherate; sodium hydrogencarbonate; 3-chloro-benzenecarboperoxoic acid; In dichloromethane;
DOI:10.1021/ja00141a036