C₁₆H₁₄Br₄O₄

Base Information

• Chemical Name: C₁₆H₁₄Br₄O₄
• CAS No.: 1359979-67-1
• Molecular Formula: C₁₆H₁₄Br₄O₄
• Molecular Weight: 589.901
• Mol file: 1359979-67-1.mol

Synonyms:C₁₆H₁₄Br₄O₄

Chemical Property of C₁₆H₁₄Br₄O₄

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of C₁₆H₁₄Br₄O₄

There total 1 articles about C₁₆H₁₄Br₄O₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

benzaldehyde (100-52-7) + 1,4,5,6-tetrabromo-7,7-dimethoxybicyclo[2.2.1]hept-5-ene-2,3-diol (819070-96-7) → C16H14Br4O4 (1359979-67-1)

Guidance literature:

With toluene-4-sulfonic acid; In benzene; for 11h; optical yield given as %de; Reflux;

DOI:10.1021/jo3000173

Reference yield: 78.0%

C16H14Br4O4 (1359979-67-1) → 3-(benzyloxy)-1,4,5,6-tetrabromo-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-ol

Guidance literature:

With diisobutylaluminium hydride; In toluene; at -10 - 20 ℃; for 14h;

DOI:10.1021/jo3000173

Reference yield:

C16H14Br4O4 (1359979-67-1) → 3-(benzyloxy)-1,4,5,6-tetrabromo-7,7-dimethoxybicyclo[2.2.1]hept-5-en-2-one

Guidance literature:

Multi-step reaction with 2 steps

1: diisobutylaluminium hydride / toluene / 14 h / -10 - 20 °C

2: pyridine; chromium(VI) oxide / dichloromethane / 90 h / 20 °C

With pyridine; chromium(VI) oxide; diisobutylaluminium hydride; In dichloromethane; toluene;

DOI:10.1021/jo3000173

upstream raw materials:

benzaldehyde

1,4,5,6-tetrabromo-7,7-dimethoxybicyclo[2.2.1]hept-5-ene-2,3-diol