(S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

Base Information

Chemical Name:(S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate
CAS No.:1442433-24-0
Molecular Formula:C₃₂H₄₄O₈
Molecular Weight:556.697
Hs Code.:

Synonyms:(S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

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Chemical Property of (S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

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Technology Process of (S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

There total 16 articles about (S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 1190042-35-3
(5S)-5-[(4-methoxybenzyl)oxy-]6-heptenoic acid

: 1442433-23-9
(4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-en-1-ol

: 1442433-24-0
(S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

Guidance literature:: (5S)-5-[(4-methoxybenzyl)oxy-]6-heptenoic acid; With dmap; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; In dichloromethane; at 0 ℃; for 0.5h; Inert atmosphere;

(4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-en-1-ol; In dichloromethane; at 0 - 20 ℃; for 12h; Inert atmosphere;
DOI:10.1016/j.tetlet.2013.04.069

Reference yield:

: 1442433-21-7
(S)-5-((S)-1-(4-methoxybenzyloxy)allyl)-11,11-dimethyl-10,10-diphen yl-2,4,9-trioxa-10-silado decane

: 1442433-24-0
(S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

Guidance literature:: Multi-step reaction with 2 steps

1.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 0 - 20 °C / Inert atmosphere

2.1: dmap; triethylamine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

2.2: 12 h / 0 - 20 °C / Inert atmosphere

With dmap; tetrabutyl ammonium fluoride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.tetlet.2013.04.069

Reference yield:

: 1007401-44-6
((2S,3S)-2-(4-(tert-butyldiphenylsilyloxy)butyl)oxiran-2-yl)methanol

: 1442433-24-0
(S)-((4S,5S)-5-((4-methoxybenzyl)oxy)-4-(methoxymethoxy)hept-6-enyl) 5-((4-methoxybenzyl)oxy)hept-6-enoate

Guidance literature:: Multi-step reaction with 6 steps

1.1: triphenylphosphine; 1H-imidazole; iodine / tetrahydrofuran / 0.17 h / 0 °C

2.1: sodium hydride / tetrahydrofuran / 4 h / 0 °C

3.1: tetrabutyl ammonium fluoride / tetrahydrofuran / 4 h / 20 °C

4.1: 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione / dimethyl sulfoxide / 4 h / 20 °C

5.1: sodium chlorite; 2-methyl-but-2-ene; sodium dihydrogenphosphate / tetrahydrofuran; tert-butyl alcohol; water / 3 h / 0 - 20 °C

6.1: dmap; triethylamine; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride / dichloromethane / 0.5 h / 0 °C / Inert atmosphere

6.2: 12 h / 0 - 20 °C / Inert atmosphere

With 1H-imidazole; dmap; sodium chlorite; sodium dihydrogenphosphate; 2-methyl-but-2-ene; tetrabutyl ammonium fluoride; iodine; sodium hydride; 1-ethyl-(3-(3-dimethylamino)propyl)-carbodiimide hydrochloride; triethylamine; triphenylphosphine; 1-hydroxy-3H-benz[d][1,2]iodoxole-1,3-dione; In tetrahydrofuran; dichloromethane; water; dimethyl sulfoxide; tert-butyl alcohol;
DOI:10.1016/j.tetlet.2013.04.069