1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride

Base Information

• Chemical Name: 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride
• CAS No.: 1057737-32-2
• Molecular Formula: C₂₃H₃₀N₃*Cl
• Molecular Weight: 383.964
• Mol file: 1057737-32-2.mol

Synonyms:1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride

Chemical Property of 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride

There total 3 articles about 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 90.0%

N-(2-chloroethyl)-2,4,6-trimethylaniline + N-(2,4,6-trimethylphenyl)imidazole (25364-44-7) → 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride (1057737-32-2)

Guidance literature:

at 150 ℃; for 1.5h;

DOI:10.1139/V08-082

Reference yield:

2,4,6-trimethylaniline (88-05-1) → 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride (1057737-32-2)

Guidance literature:

Multi-step reaction with 3 steps

1: potassium carbonate / acetonitrile / 48 h / 20 °C / Inert atmosphere

2: dimethylsulfide borane complex / tetrahydrofuran / 24 h / 0 - 20 °C / Inert atmosphere

3: 15 h / 140 °C / Inert atmosphere

With dimethylsulfide borane complex; potassium carbonate; In tetrahydrofuran; acetonitrile;

DOI:10.1021/acs.organomet.6b00925

Reference yield:

N-(chloroacetyl)-2,4,6-trimethylaniline (3910-51-8) → 1-(2,4,6-trimethylphenyl)-3-(2-((2,4,6-trimethylphenyl)amino)ethyl)imidazolium chloride (1057737-32-2)

Guidance literature:

Multi-step reaction with 2 steps

1: dimethylsulfide borane complex / tetrahydrofuran / 24 h / 0 - 20 °C / Inert atmosphere

2: 15 h / 140 °C / Inert atmosphere

With dimethylsulfide borane complex; In tetrahydrofuran;

DOI:10.1021/acs.organomet.6b00925

upstream raw materials:

N-(2,4,6-trimethylphenyl)imidazole

2,4,6-trimethylaniline

N-(chloroacetyl)-2,4,6-trimethylaniline

Downstream raw materials:

2,4,6-Me₃C₆H₂NC₃H₂NCH₂CH₂NH-2,4,6-Me₃C₆H₂