Benzyl 2-nitrophenyl sulfoxide

Base Information

• Chemical Name: Benzyl 2-nitrophenyl sulfoxide
• CAS No.: 35804-36-5
• Molecular Formula: C₁₃H₁₁NO₃S
• Molecular Weight: 261.301
• European Community (EC) Number: 666-255-0
• Nikkaji Number: J3.296.416H
• Mol file: 35804-36-5.mol

Synonyms:Benzyl 2-nitrophenyl sulfoxide;35804-36-5;1-benzylsulfinyl-2-nitrobenzene;1-(Benzylsulfinyl)-2-nitrobenzene;1-nitro-2-phenylmethanesulfinylbenzene;benzyl(2-nitrophenyl)oxo-lambda~4~-sulfane;Benzyl (2-nitrophenyl)oxo-sulfane;MFCD00159077;AKOS015993467;7W-0020;SR-01000306894;SR-01000306894-1

Chemical Property of Benzyl 2-nitrophenyl sulfoxide

Chemical Property:

• XLogP3: 2.5
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 4
• Rotatable Bond Count: 3
• Exact Mass: 261.04596439
• Heavy Atom Count: 18
• Complexity: 310

Purity/Quality:

98%,99%, ^*data from raw suppliers

BENZYL 2-NITROPHENYL SULFOXIDE Aldrich ^*data from reagent suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

• Canonical SMILES: C1=CC=C(C=C1)CS(=O)C2=CC=CC=C2[N+](=O)[O-]

Technology Process of Benzyl 2-nitrophenyl sulfoxide

There total 3 articles about Benzyl 2-nitrophenyl sulfoxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

1-(benzylsulfanyl)-2-nitrobenzene (22057-44-9) → 2-nitrophenyl benzyl sulfoxide (35804-36-5)

Guidance literature:

With C₄₀H₃₂CuN₂O₂S₂; dihydrogen peroxide; In water; acetonitrile; at 20 ℃; for 6h; chemoselective reaction;

DOI:10.1016/j.tetlet.2013.12.073

Reference yield: 95.0%

1-(benzylsulfanyl)-2-nitrobenzene (22057-44-9) → 2-nitrophenyl benzyl sulfoxide (35804-36-5) + benzyl 2-nitrophenyl sulphone (32018-42-1)

Guidance literature:

With C₄₀H₃₂CuN₂O₂S₂; dihydrogen peroxide; In water; acetonitrile; at 20 ℃; for 6h; Reagent/catalyst; Solvent; chemoselective reaction; Catalytic behavior;

DOI:10.1016/j.tetlet.2013.12.073

Reference yield:

→ 2-nitrophenyl benzyl sulfoxide (35804-36-5)

Guidance literature:

2-Nitrophenyl-benzyl-sulfid, H2O2, Oxid.;

DOI:10.1021/ja00755a021

upstream raw materials:

1-(benzylsulfanyl)-2-nitrobenzene

Refernces

• 1、 Gogoi, Prasanta,Hazarika, Sukanya,Barman, Pranjit. "Tetrabutylammonium tribromide impregnated MCM-48 as a heterogeneous catalyst for selective oxidation of sulfides". . p. 38044 - 38047. Retrieved 2015/06/30.
• 2、 Gogoi, Prasanta,Kalita, Mukul,Bhattacharjee, Tirtha,Barman, Pranjit. "Copper-Schiff base complex catalyzed oxidation of sulfides with hydrogen peroxide". supporting information. p. 1028 - 1030. Retrieved 2015/02/05.