(η6-C6Me6)Ru(OCOCF3)2(PPh3)

Base Information

• Chemical Name: (η6-C6Me6)Ru(OCOCF3)2(PPh3)
• CAS No.: 82498-35-9
• Molecular Formula: C₃₄H₃₃F₆O₄PRu
• Molecular Weight: 751.668
• Mol file: 82498-35-9.mol

Synonyms:

Chemical Property of (η6-C6Me6)Ru(OCOCF3)2(PPh3)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of (η6-C6Me6)Ru(OCOCF3)2(PPh3)

There total 3 articles about (η6-C6Me6)Ru(OCOCF3)2(PPh3) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 71.0%

(η(6)-C6Me6)Ru(Me)2(PPh3) + trifluoroacetic acid (76-05-1) → (η6-C6Me6)Ru(OCOCF3)2(PPh3) (82498-35-9)

Guidance literature:

In benzene; byproducts: CH4; an excess of CF3COOH was added at room temp. under inert atmosphere to a soln. of Ru-complex in benzene, after gas evolution had finished the soln. was stirred for 10 min; volatiles were removed in vacuo, residue recrystd. from benzene-hexane;elem anal.;

DOI:10.1016/S0022-328X(00)84330-2

Reference yield: 61.0%

[bis(trifluoroacetato)-(η-hexamethylbenzene)-ruthenium] hydrate (90721-10-1) → (η6-C6Me6)Ru(OCOCF3)2(PPh3) (82498-35-9)

Guidance literature:

With triphenylphosphine; In benzene; mixt. of Ru-complex and PPh3 in benzene was stirred at room temp. for 3.5 h under N2; solvent was evapd. under reduced pressure, n-hexane was added, dried invac.; elem. anal.;

Reference yield:

(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II) (82498-46-2) + thallium(I) trifluoroacetate (2923-19-5) → (η6-C6Me6)Ru(OCOCF3)2(PPh3) (82498-35-9)

Guidance literature:

In benzene; 2 equiv of CF3COOTl were added at room temp. under inert atmosphere to a soln. of Ru-complex in benzene, the mixt. was stirred for 15 min; the soln. was filtered, hexane added to the filtrate, ppt. was collected and recrystd. from benzene-hexane;

DOI:10.1016/S0022-328X(00)84330-2

upstream raw materials:

[bis(trifluoroacetato)-(η-hexamethylbenzene)-ruthenium] hydrate

trifluoroacetic acid

(η(6)-hexamethylbenzene)dichloro(PPh3)ruthenium(II)

thallium(I) trifluoroacetate

Downstream raw materials:

hexamethylbenzene-dihydrido-triphenylphosphine-ruthenium(II)

(η6-C6Me6)RuH(OCOCF3)(PPh3)