methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

Base Information

Chemical Name:methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate
CAS No.:1287768-30-2
Molecular Formula:C₃₅H₃₂O₉S
Molecular Weight:628.7
Hs Code.:

Synonyms:methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

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Chemical Property of methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

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Technology Process of methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

There total 6 articles about methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 1287768-28-8
phenyl 2,3-di-O-benzoyl-4,6-O-p-methoxy-benzylidene-1-thio-β-D-glucopyranoside

: 1287768-30-2
methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

Guidance literature:: Multi-step reaction with 3 steps

1.1: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere

2.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

3.1: caesium carbonate / N,N-dimethyl-formamide / 0 °C

3.2: 1 h / 0 °C

With triethylsilane; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; phenylborondichloride; caesium carbonate; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo200076z

Reference yield:

: 1287768-29-9
phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside

: 1287768-30-2
methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

Guidance literature:: Multi-step reaction with 2 steps

1.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

2.1: caesium carbonate / N,N-dimethyl-formamide / 0 °C

2.2: 1 h / 0 °C

With 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; caesium carbonate; In dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo200076z

Reference yield:

: 71676-30-7,87508-18-7,138922-03-9,87508-17-6
(2R,4aR,6S,7R,8R,8aS)-2-Phenyl-6-phenylsulfanyl-hexahydro-pyrano[3,2-d][1,3]dioxine-7,8-diol

: 1287768-30-2
methyl phenyl 2,3-di-O-benzoyl-4-O-p-methoxybenzyl-1-thio-β-D-glucuronate

Guidance literature:: Multi-step reaction with 6 steps

1.1: pyridine / 0 - 20 °C

2.1: toluene-4-sulfonic acid / methanol; dichloromethane / 8 h / 35 °C

3.1: camphor-10-sulfonic acid / N,N-dimethyl-formamide / 1 h / 50 °C

4.1: triethylsilane; phenylborondichloride / dichloromethane / 0.5 h / -78 °C / Molecular sieve; Inert atmosphere

5.1: 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene / dichloromethane; water / 20 °C

6.1: caesium carbonate / N,N-dimethyl-formamide / 0 °C

6.2: 1 h / 0 °C

With pyridine; triethylsilane; 2,2,6,6-Tetramethyl-1-piperidinyloxy free radical; [bis(acetoxy)iodo]benzene; camphor-10-sulfonic acid; phenylborondichloride; caesium carbonate; toluene-4-sulfonic acid; In methanol; dichloromethane; water; N,N-dimethyl-formamide;
DOI:10.1021/jo200076z