o-chlorophenylphosphonous dichloride

Base Information

• Chemical Name: o-chlorophenylphosphonous dichloride
• CAS No.: 1004-78-0
• Molecular Formula: C₆H₄Cl₃P
• Molecular Weight: 213.431
• Mol file: 1004-78-0.mol

Synonyms:o-chlorophenylphosphonous dichloride

Chemical Property of o-chlorophenylphosphonous dichloride

Chemical Property:

• Boiling Point: 76-77 °C(Press: 0.53 Torr)
• Density: 1.466 g/cm3

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of o-chlorophenylphosphonous dichloride

There total 3 articles about o-chlorophenylphosphonous dichloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

chlorobenzene (108-90-7) → o-chlorophenylphosphonous dichloride (1004-78-0) + 4-chlorophenyldichlorophosphine (1005-33-0)

Guidance literature:

With aluminum (III) chloride; phosphorus trichloride; at 80 ℃; for 6h; Inert atmosphere;

DOI:10.1016/j.apcata.2020.117943

Reference yield:

chlorobenzene (108-90-7) → o-chlorophenylphosphonous dichloride (1004-78-0) + m-chlorophenylphosphonous dichloride (1718-21-4) + 4-chlorophenyldichlorophosphine (1005-33-0)

Guidance literature:

With aluminium trichloride; phosphorus trichloride;

DOI:10.1016/0040-4020(82)80240-8

Reference yield:

→ o-chlorophenylphosphonous dichloride (1004-78-0)

Guidance literature:

2-Chlor-benzoldiazonium-fluoroborat, E. (Suspension), 1. PCl3, CuBr, N2 (-> nicht isoliertes Zwischenprodukt), 2. Mg, 30-50grad;

DOI:10.1021/ja01481a004

upstream raw materials:

chlorobenzene

Downstream raw materials:

2-chlorophenylphosphoryl dichloride

C₆H₄ClF₄P

Refernces

• 1、 Harger, Martin J.P.,Westlake, Sally. "DIARYLPHOSPHINIC AZIDES. PHOTOCHEMICAL REACTIONS INCLUDING REARRANGEMENT IN METHANOL". . p. 1511 - 1516. Retrieved 2007/10/02.