C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*Cl^(1-)

Base Information

• Chemical Name: C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*Cl^(1-)
• CAS No.: 80319-87-5
• Molecular Formula: C₂₅H₃₂N₄Rh*Cl
• Molecular Weight: 526.914
• Mol file: 80319-87-5.mol

Synonyms:C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*Cl^(1-)

Chemical Property of C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*Cl^(1-)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*Cl^(1-)

There total 2 articles about C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*Cl^(1-) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 77.0%

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6) + 1,1’-((phenyl)methylene)bis(3,5-dimethyl-1H-pyrazole) (124225-83-8) → C6H5CH(C3H(CH3)2N2)2Rh(C8H12)(1+)*Cl(1-) (80319-87-5)

Guidance literature:

In benzene; soln. of 1:2 stoich. ratio of ligand and Rh-complex was stirred at roomtemp. for 6 h; ppt. filtered off, washed with hexane; elem. anal.;

DOI:10.1016/S0022-328X(00)90026-3

Reference yield:

C6H5CH(C3H(CH3)2N2)2Rh(C2H4)2Cl (80319-86-4) + cyclo-octa-1,5-diene (5259-72-3,10060-40-9,111-78-4) → C6H5CH(C3H(CH3)2N2)2Rh(C8H12)(1+)*Cl(1-) (80319-87-5)

Guidance literature:

In benzene; stirring at room temp. for 20 h;

DOI:10.1016/S0022-328X(00)90026-3

Reference yield: 75.0%

C6H5CH(C3H(CH3)2N2)2Rh(C8H12)(1+)*Cl(1-) (80319-87-5) → di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium (12092-47-6)

Guidance literature:

With HCl; In methanol; byproducts: 3,5-dimethylpyrazole hydrochloride; soln. of Rh-complex was frozen by liquid N2, anhydous HCl was added, warmed to room temp.; ppt. filtered off, washed with methanol;

DOI:10.1016/S0022-328X(00)90026-3

upstream raw materials:

C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₂H₄)2Cl

cyclo-octa-1,5-diene

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

1,1’-((phenyl)methylene)bis(3,5-dimethyl-1H-pyrazole)

Downstream raw materials:

di-μ-chloro-bis(1,5-cyclooctadiene)dirhodium

RhCl(1,5-cyclooctadiene)(PPh₃)

C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)⁽¹⁺⁾*B(C₆H₅)4^(1-)=C₆H₅CH(C₃H(CH₃)2N₂)2Rh(C₈H₁₂)B(C₆H₅)4

C₆H₅CH(C₃H₃N₂)2(RhC₈H₁₂Cl)2

Refernces