1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol

Base Information

• Chemical Name: 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol
• CAS No.: 74948-52-0
• Molecular Formula: C₃₀H₃₀O₁₁S
• Molecular Weight: 598.628
• Mol file: 74948-52-0.mol

Synonyms:1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol

Chemical Property of 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol

There total 2 articles about 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol (74948-51-9) → 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol (74948-52-0)

Guidance literature:

With hydrogenchloride; In water; acetone; for 1.5h; Heating;

DOI:10.1016/S0008-6215(00)85702-X

Reference yield:

methyl 6-acetoxymercuri(II)-3,4-di-O-benzoyl-6-deoxy-5-methoxy-2-O-toluene-p-sulphonyl-α-D-glucopyranoside → 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol (74948-52-0)

Guidance literature:

Multi-step reaction with 2 steps

1: 60 percent / dimethylformamide; pyridine / 2 h / Ambient temperature

2: 100 percent / hydrochloric acid (2M) / acetone; H₂O / 1.5 h / Heating

With hydrogenchloride; In pyridine; water; N,N-dimethyl-formamide; acetone;

DOI:10.1016/S0008-6215(00)85702-X

upstream raw materials:

1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol