1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol

Base Information

• Chemical Name: 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol
• CAS No.: 74948-51-9
• Molecular Formula: C₃₁H₃₂O₁₁S
• Molecular Weight: 612.654
• Mol file: 74948-51-9.mol

Synonyms:1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol

Chemical Property of 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol

There total 1 articles about 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 60.0%

methyl 6-acetoxymercuri(II)-3,4-di-O-benzoyl-6-deoxy-5-methoxy-2-O-toluene-p-sulphonyl-α-D-glucopyranoside + acetyl chloride (75-36-5) → 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol (74948-51-9)

Guidance literature:

In pyridine; N,N-dimethyl-formamide; for 2h; Ambient temperature;

DOI:10.1016/S0008-6215(00)85702-X

Reference yield: 100.0%

1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1,5-di-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hex-5-enose aldehydrol (74948-51-9) → 1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol (74948-52-0)

Guidance literature:

With hydrogenchloride; In water; acetone; for 1.5h; Heating;

DOI:10.1016/S0008-6215(00)85702-X

upstream raw materials:

acetyl chloride

Downstream raw materials:

1(S)-1-O-acetyl-3,4-di-O-benzoyl-6-deoxy-1-O-methyl-2-O-toluene-p-sulphonyl-D-xylo-hexos-5-ulose aldehydrol