2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

Base Information

Chemical Name:2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane
CAS No.:81712-87-0
Molecular Formula:C₁₃H₁₈O₈
Molecular Weight:302.281
Hs Code.:

Synonyms:2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

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Chemical Property of 2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

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Technology Process of 2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

There total 8 articles about 2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 97.0%

: 81712-86-9
2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-2,3-O-isopropyliden-1-C-methylenpentahydroxycyclohexane

: 81712-87-0
2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

Guidance literature:: With acetic acid; In tetrahydrofuran; water; at 70 ℃; for 7h;
DOI:10.1016/S0008-6215(00)88052-0

Reference yield:

: 81712-81-4
1L-2,3,4-Tri-O-benzyl-1-C-hydroxymethyl-5,6-O-isopropyliden-chiro-inositol

: 81712-87-0
2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

Guidance literature:: Multi-step reaction with 6 steps

1: 81 percent / pyridine / 20 h / 60 °C

2: 94 percent / hydrogen / 10 percent palladium-carbon / dioxane; acetic acid / 0.33 h / Ambient temperature

3: sodium methoxide / methanol / 0.25 h / 0 °C

4: pyridine

5: 61 percent / 3-methyl-2-selenoxobenzothiazole, trifluoroacetic acid / CH₂Cl₂ / 20 h / Ambient temperature

6: 97 percent / acetic acid / tetrahydrofuran; H₂O / 7 h / 70 °C

With pyridine; N-methyl-1,3-benzothiazole-2(3H)-selone; hydrogen; sodium methylate; acetic acid; trifluoroacetic acid; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; water; acetic acid;
DOI:10.1016/S0008-6215(00)88052-0

Reference yield:

: 81712-79-0
1L-7-O-Benzoyl-2,3,4-tri-O-benzyl-1-C-hydroxymethyl-chiro-inositol

: 81712-87-0
2L-(2,3,5/4,6)-4,5,6-Tri-O-acetyl-1-C-methylenpentahydroxycyclohexane

Guidance literature:: Multi-step reaction with 8 steps

1: 1.) p-toluene-sulphonic acid; 2.) triethylamine / 1.) THF, 4 h, 70 deg C

2: sodium methoxide / methanol / 20 h / Ambient temperature

3: 81 percent / pyridine / 20 h / 60 °C

4: 94 percent / hydrogen / 10 percent palladium-carbon / dioxane; acetic acid / 0.33 h / Ambient temperature

5: sodium methoxide / methanol / 0.25 h / 0 °C

6: pyridine

7: 61 percent / 3-methyl-2-selenoxobenzothiazole, trifluoroacetic acid / CH₂Cl₂ / 20 h / Ambient temperature

8: 97 percent / acetic acid / tetrahydrofuran; H₂O / 7 h / 70 °C

With pyridine; N-methyl-1,3-benzothiazole-2(3H)-selone; hydrogen; sodium methylate; toluene-4-sulfonic acid; acetic acid; triethylamine; trifluoroacetic acid; palladium on activated charcoal; In tetrahydrofuran; 1,4-dioxane; methanol; dichloromethane; water; acetic acid;
DOI:10.1016/S0008-6215(00)88052-0