cis,mer-{IrH₂(C₂H₄)(PMe₂Ph)3}BF₄

Base Information

• Chemical Name: cis,mer-{IrH₂(C₂H₄)(PMe₂Ph)3}BF₄
• CAS No.: 124599-97-9
• Molecular Formula: BF₄*C₂₆H₃₉IrP₃
• Molecular Weight: 723.542

Synonyms:cis,mer-{IrH₂(C₂H₄)(PMe₂Ph)3}BF₄

Chemical Property of cis,mer-{IrH₂(C₂H₄)(PMe₂Ph)3}BF₄

Chemical Property:

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Technology Process of cis,mer-{IrH₂(C₂H₄)(PMe₂Ph)3}BF₄

There total 4 articles about cis,mer-{IrH₂(C₂H₄)(PMe₂Ph)3}BF₄ which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

{Ir(CH2CH2)2(P(CH3)2(C6H5))3}(1+)*BF4(1-) = {Ir(CH2CH2)2(P(CH3)2(C6H5))3}BF4 (115983-34-1) → cis,mer-{IrH2(C2H4)(PMe2Ph)3}BF4 (124599-97-9)

Guidance literature:

With H₂; In neat (no solvent); byproducts: ethylene; under N2 or vac.; Ir-complex degassed, pressurized with excess of H2, sealed, shaken 10min; not isolated, detected by NMR;

DOI:10.1021/ja00158a054

Reference yield:

{Ir(η2-H2)H2(PMe2Ph)3}BF4 (115983-32-9) + ethene (74-85-1) → cis,mer-{IrH2(C2H4)(PMe2Ph)3}BF4 (124599-97-9)

Guidance literature:

In not given; byproducts: H2; under N2 or vac.; at -50°C, excess of ethylene; not isolated, detcted by NMR;

DOI:10.1021/ja00158a054

Reference yield:

{Ir(η2-H2)H2(PMe2Ph)3}BF4 (115983-32-9) → cis,mer-(IrH2(CH2CH2)(PMe2Ph)3)(BF4) (124599-97-9)

Guidance literature:

With ethylene; In dichloromethane-d2; excess ethylene, -50°C; not isolated, detected by (1)H-NMR;

upstream raw materials:

{Ir(η2-H2)H2(PMe2Ph)3}BF4

Ir(C₂H₄)2(P(CH₃)2(C₆H₅))3⁽¹⁺⁾*BF₄^(1-)=(Ir(C₂H₄)2(P(CH₃)2(C₆H₅))3)(BF₄)

ethene

{Ir(CH₂CH₂)2(P(CH₃)2(C₆H₅))3}⁽¹⁺⁾*BF₄^(1-) = {Ir(CH₂CH₂)2(P(CH₃)2(C₆H₅))3}BF₄

Downstream raw materials:

{Ir(CH₂CH₂)2(P(CH₃)2(C₆H₅))3}⁽¹⁺⁾*BF₄^(1-) = {Ir(CH₂CH₂)2(P(CH₃)2(C₆H₅))3}BF₄

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