p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

Base Information

Chemical Name:p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside
CAS No.:1272616-88-2
Molecular Formula:C₁₉H₂₆O₆
Molecular Weight:350.412
Hs Code.:

Synonyms:p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

Chemical Property:

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Technology Process of p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

There total 1 articles about p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 1096154-15-2
4-methoxyphenyl 6-deoxy-2,3-O-isopropylidene-α-L-talopyranoside

: 106-95-6
allyl bromide

: 1272616-88-2
p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

Guidance literature:: With sodium hydride; In N,N-dimethyl-formamide; at 0 - 20 ℃;
DOI:10.3390/molecules16021113

Reference yield:

: 1272616-88-2
p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

: C₅₀H₆₆O₉

Guidance literature:: Multi-step reaction with 7 steps

1: acetic acid / 2 h / Heating

2: pyridine / 20 °C

3: ammonium cerium (IV) nitrate / acetonitrile / 0.33 h / 35 °C

4: 1,8-diazabicyclo[5.4.0]undec-7-ene / dichloromethane / 4 h / Inert atmosphere

5: trimethylsilyl trifluoromethanesulfonate / dichloromethane / 2 h / -10 - 20 °C / Molecular sieve; Inert atmosphere

6: palladium dichloride / methanol; dichloromethane / 12 h / 20 °C

7: palladium 10% on activated carbon; hydrogen / ethyl acetate / 12 h / Reflux

With pyridine; ammonium cerium (IV) nitrate; trimethylsilyl trifluoromethanesulfonate; palladium 10% on activated carbon; hydrogen; acetic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; palladium dichloride; In methanol; dichloromethane; ethyl acetate; acetonitrile;
DOI:10.3390/molecules16021113

Reference yield:

: 1272616-88-2
p-methoxyphenyl 4-O-allyl-2,3-O-isopropylidene-6-deoxy-α-L-talopyranoside

: C₂₃H₂₄O₇

Guidance literature:: Multi-step reaction with 3 steps

1: acetic acid / 2 h / Heating

2: pyridine / 20 °C

3: ammonium cerium (IV) nitrate / acetonitrile / 0.33 h / 35 °C

With pyridine; ammonium cerium (IV) nitrate; acetic acid; In acetonitrile;
DOI:10.3390/molecules16021113