9-Bromo-10-phenylanthracene

Base Information

• Chemical Name: 9-Bromo-10-phenylanthracene
• CAS No.: 23674-20-6
• Molecular Formula: C20H13Br
• Molecular Weight: 333.227
• Hs Code.: 29039990
• European Community (EC) Number: 621-755-8
• DSSTox Substance ID: DTXSID60400022
• Nikkaji Number: J548.828A
• Wikidata: Q72449211
• Mol file: 23674-20-6.mol

Synonyms:9-bromo-10-phenylanthracene;23674-20-6;Anthracene, 9-bromo-10-phenyl-;9-bromo-10-phenyl-anthracene;MFCD00230983;10-bromo-9-phenylanthracene;C20H13Br;9-bromo10-phenylanthracene;9-Phenyl-10-bromanthracen;9-phenyl-10-bromoanthracene;SCHEMBL295397;9-bromo-10-phenyl anthracene;9-bromo-10-(phenyl)anthracene;AMY8613;DTXSID60400022;WHGGVVHVBFMGSG-UHFFFAOYSA-N;AKOS015912825;CS-W011944;DS-3834;AC-24438;SY033980;B3977;FT-0655096;A21256;I10202;J-015182;J-519498;9-Bromo-10-phenylanthracene

Chemical Property of 9-Bromo-10-phenylanthracene

Chemical Property:

• Vapor Pressure: 7.45E-08mmHg at 25°C
• Melting Point: 154-155 °C
• Refractive Index: 1.717
• Boiling Point: 449.7 °C at 760 mmHg
• Flash Point: 221.3 °C
• PSA: 0.00000
• Density: 1.393 g/cm³
• LogP: 6.42250
• Storage Temp.: Sealed in dry,Room Temperature
• Solubility.: Chloroform, Methanol (Slightly)
• Water Solubility.: Insoluble in water. Soluble in hot toluene, dimethylformamide.
• XLogP3: 6.7
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 0
• Rotatable Bond Count: 1
• Exact Mass: 332.02006
• Heavy Atom Count: 21
• Complexity: 322

Purity/Quality:

99% ^*data from raw suppliers

9-Bromo-10-phenylanthracene ^*data from reagent suppliers

Safty Information:

• Safety Statements: 24/25

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: C1=CC=C(C=C1)C2=C3C=CC=CC3=C(C4=CC=CC=C42)Br
• Uses: It is used as an OLED material. 9-Bromo-10-phenylanthracene is an anthracene compound for proteomics research.

Technology Process of 9-Bromo-10-phenylanthracene

There total 29 articles about 9-Bromo-10-phenylanthracene which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

9-phenylanthracene (602-55-1) → 9-bromo-10-phenylanthracene (23674-20-6)

Guidance literature:

With N-Bromosuccinimide; In chloroform; at 60 ℃; for 1h; Temperature; Time; Inert atmosphere;

DOI:10.1039/c3tc30319e

Reference yield: 86.4%

9,10-Dibromoanthracene (523-27-3) + phenylboronic acid (98-80-6) → 9-bromo-10-phenylanthracene (23674-20-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; water; toluene; at 80 ℃; Inert atmosphere;

DOI:10.1021/jacs.0c07727

Reference yield: 84.0%

9-bromo-10-iodo-anthracene (359435-47-5) + 2-phenyl-4,4,5,5-tetramethyl-1,3,2-dioxoborole (24388-23-6) → 9-bromo-10-phenylanthracene (23674-20-6)

Guidance literature:

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; potassium carbonate; In ethanol; water; toluene; at 85 ℃; for 12h; Inert atmosphere;

upstream raw materials:

9-phenylanthracene

α,α'-diphenylphthalyl bromide

pyridine

bromine

Downstream raw materials:

9-phenylanthracene

9,10-phenanthrenequinone

phenoxy-9 phenyl-10 anthracene

10-phenyl-9-anthracenecarbonitrile

Refernces

• 1、 Olesund, Axel,Gray, Victor,M?rtensson, Jerker,Albinsson, Bo. "Diphenylanthracene Dimers for Triplet-Triplet Annihilation Photon Upconversion: Mechanistic Insights for Intramolecular Pathways and the Importance of Molecular Geometry". supporting information. p. 5745 - 5754. Retrieved 2021/05/06.
• 2、 -. "Compound, organic luminescent material and organic electroluminescent device". Paragraph 0127; 0128; 0130; 0136; 0137; 0139. . Retrieved 2021/08/19.