μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum

Base Information

• Chemical Name: μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum
• CAS No.: 199334-49-1
• Molecular Formula: C₃₂H₆₄F₆O₆P₄Pt₂S₂
• Molecular Weight: 1237.03
• Mol file: 199334-49-1.mol

Synonyms:μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum

Chemical Property of μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum

Chemical Property:

Purity/Quality:

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MSDS Files:

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Technology Process of μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum

There total 1 articles about μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

1,4-bis(iodobis(triethylphosphine)platinum)phenylene (188829-89-2) + silver trifluoromethanesulfonate (2923-28-6) → μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum (199334-49-1)

Guidance literature:

In dichloromethane; byproducts: AgI; (N2); stirring (0°C, dark, 2 h); filtration (room temp., AgI removal), addn. of diethyl ether, freezing (1-2 d), filtration (N2), drying (vac., 40°C); elem. anal.;

DOI:10.1021/ja972668s

Reference yield: 96.0%

μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum (199334-49-1) + C38H20N2 (1431045-58-7) → 12CF3O3S(1-)*6C6H4(2-)*24C6H15P*6C38H20N2*12Pt(2+)

Guidance literature:

In dichloromethane-d2; at 20 ℃; for 4h;

DOI:10.1021/om301108s

Reference yield: 95.0%

5,10-bis(4-pyridyl)-15,20-bis(phenyl)porphyrin + μ-1,4-phenylenetetrakis(triethylphosphine)bis(1,1,1-trifluoromethanesulfonato-κO)diplatinum (199334-49-1) → 8Pt(2+)*4C42H28N6*16P(C2H5)3*4C6H4(2-)*8CF3SO3(1-)=[C42H28N6(Pt(P(C2H5)3)2)2C6H4]4[O3SCF3]8

Guidance literature:

In dichloromethane; dry N2-atmosphere; stirring (room temp., 1 h); concg. (vac.), pptn. on Et2O addn., drying (vac.); elem. anal.;

DOI:10.1021/ja9839825

upstream raw materials:

1,4-bis(iodobis(triethylphosphine)platinum)phenylene

silver trifluoromethanesulfonate