1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole

Base Information

• Chemical Name: 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole
• CAS No.: 1146340-38-6
• Molecular Formula: C₂₅H₂₅BN₂O₂
• Molecular Weight: 396.297
• Mol file: 1146340-38-6.mol

Synonyms:1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole

Chemical Property of 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole

Chemical Property:

• Boiling Point: 564.0±52.0 °C(Predicted)
• Density: 1.12±0.1 g/cm3(Predicted)

Purity/Quality:

98.5% ^*data from raw suppliers

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole

There total 17 articles about 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole (2620-76-0) + bis(pinacol)diborane (73183-34-3) → 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole (1146340-38-6)

Guidance literature:

With (1,1'-bis(diphenylphosphino)ferrocene)palladium(II) dichloride; potassium acetate; In 1,4-dioxane; at 80 ℃; Inert atmosphere;

Reference yield: 81.0%

1,1'-Bis(diphenylphosphino)ferrocene]dichloropalladium (Pd(dppf)Cl2) + 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole (2620-76-0) + bis(pinacol)diborane (73183-34-3) → 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole (1146340-38-6)

Guidance literature:

With potassium acetate; In 1,4-dioxane;

Reference yield: 81.0%

bis(diphenylphosphino)ferrocene]dichloropalladium (Pd(dppf)Cl2) + potassium acetate (KOAc) + 2-(4-bromophenyl)-1-phenyl-1H-benzimidazole (2620-76-0) + bis(pinacol)diborane (73183-34-3) → 1-phenyl-2-[4-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-phenyl]-1H-benzo[d]imidazole (1146340-38-6)

Guidance literature:

In 1,4-dioxane;

upstream raw materials:

2-(4-bromophenyl)-1-phenyl-1H-benzimidazole

bis(pinacol)diborane

4-chlorobenzoyl chloride

N-phenyl-1,2-benzenediamine

Downstream raw materials:

2-tert-butyl-9,10-bis[4'-(1-phenylbenzoimidazyl)biphenyl-4-yl]anthracene

(2-(benzo[d]oxazol-2-yl)phenyl)-4,4,5,5-tetramethyl-1,3,2-dioxaborolane

9-(4'-(1-phenyl-1H-benzo[d]imidazol-2-yl)biphenyl-4-yl)-9H-carbazole

C₃₉H₃₁N₃