(E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

Base Information

Chemical Name:(E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one
CAS No.:949463-65-4
Molecular Formula:C₃₈H₆₄O₄
Molecular Weight:584.924
Hs Code.:

Synonyms:(E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

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Chemical Property of (E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

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Technology Process of (E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

There total 3 articles about (E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 949463-62-1
dimethyl 15-(benzyloxy)-2-oxopentadecylphosphonate

: 949463-64-3
(4R,5S)-5-decyl-2,2-dimethyl-1,3-dioxolane-4-carbaldehyde

: 949463-65-4
(E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

Guidance literature:: With 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; In acetonitrile; at 20 ℃; for 1h;
DOI:10.1021/jo070560h

Reference yield:

: 949463-61-0
methyl 14-(benzyloxy)tetradecanoate

: 949463-65-4
(E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

Guidance literature:: Multi-step reaction with 2 steps

1.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C

1.2: 93 percent / tetrahydrofuran; hexane / 2.5 h / -78 °C

2.1: 95 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene; LiCl / acetonitrile / 1 h / 20 °C

With n-butyllithium; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; In tetrahydrofuran; hexane; acetonitrile;
DOI:10.1021/jo070560h

Reference yield:

: 137442-01-4
14-(benzyloxy)tetradecanoic acid

: 949463-65-4
(E)-16-(benzyloxy)-1-((4S,5S)-5-decyl-2,2-dimethyl-1,3-dioxolan-4-yl)hexadec-1-en-3-one

Guidance literature:: Multi-step reaction with 3 steps

1.1: 94 percent / p-toluenesulfonic acid / 3 h / Heating

2.1: n-butyllithium / tetrahydrofuran; hexane / 0.5 h / -78 °C

2.2: 93 percent / tetrahydrofuran; hexane / 2.5 h / -78 °C

3.1: 95 percent / 1,8-diazabicyclo[5.4.0]undec-7-ene; LiCl / acetonitrile / 1 h / 20 °C

With n-butyllithium; toluene-4-sulfonic acid; 1,8-diazabicyclo[5.4.0]undec-7-ene; lithium chloride; In tetrahydrofuran; hexane; acetonitrile;
DOI:10.1021/jo070560h