(S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

Base Information

Chemical Name:(S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one
CAS No.:1243289-06-6
Molecular Formula:C₁₆H₂₃BO₃
Molecular Weight:274.168
Hs Code.:

Synonyms:(S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

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Technology Process of (S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

There total 4 articles about (S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 95.0%

: 34880-85-8
3-chloro-1-phenylbutan-1-one

: 73183-34-3
bis(pinacol)diborane

: 1243289-06-6
(S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

Guidance literature:: bis(pinacol)diborane; With potassium phosphate; copper(l) iodide; (S)-(-)-[(S)-2-diphenylphosphinoferrocenyl](N,N-dimethylamino)(2-diphenylphosphinophenyl)methane; In tert-Amyl alcohol; at 20 ℃; for 0.166667h; Inert atmosphere;

3-chloro-1-phenylbutan-1-one; In tert-Amyl alcohol; at 60 ℃; for 20h; enantioselective reaction; Inert atmosphere;
DOI:10.1002/cctc.201402823

Reference yield: 88.0%

: 495-41-0
1-phenylbut-2-en-1-one

: 73183-34-3
bis(pinacol)diborane

: 1243289-06-6
(S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

Guidance literature:: bis(pinacol)diborane; With copper(I) oxide; C₂₇H₂₆N₃O⁽¹⁺⁾*Cl^(1-); caesium carbonate; In toluene; at 20 ℃; Inert atmosphere;

1-phenylbut-2-en-1-one; In methanol; toluene; at 0 ℃; for 0.166667h; enantioselective reaction; Inert atmosphere;
DOI:10.1021/jo302694d

Reference yield:

: 35660-91-4,35845-66-0,495-41-0
(E)-1-phenyl-2-buten-1-one

: 73183-34-3
bis(pinacol)diborane

(R)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one: 1144528-41-5
(R)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

: 1243289-06-6
(S)-1-phenyl-3-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)butan-1-one

Guidance literature:: bis(pinacol)diborane; With caesium carbonate; (R)-2,2'-bis(diphenylphosphanyl)-1,1'-binaphthyl; In tetrahydrofuran; at 20 ℃; for 0.166667h; Inert atmosphere;

(E)-1-phenyl-2-buten-1-one; With methanol; In tetrahydrofuran; at 70 ℃; for 6h; optical yield given as %ee; enantioselective reaction; Inert atmosphere;
DOI:10.1002/anie.201001198