dicyclopentadienylphenylzirconium(IV) chloride

Base Information

Chemical Name:dicyclopentadienylphenylzirconium(IV) chloride
CAS No.:75061-73-3
Molecular Formula:C₁₆H₁₅ClZr
Molecular Weight:333.972
Hs Code.:

Synonyms:dicyclopentadienylphenylzirconium(IV) chloride

Suppliers and Price of dicyclopentadienylphenylzirconium(IV) chloride

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of dicyclopentadienylphenylzirconium(IV) chloride

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of dicyclopentadienylphenylzirconium(IV) chloride

There total 2 articles about dicyclopentadienylphenylzirconium(IV) chloride which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: [(C₅H₅)2Zr(Ph)][B(C₆F₅)4]*2.3C₆H₆

: 23616-79-7
benzyltri(n-butyl)ammonium chloride

: 75061-73-3
dicyclopentadienylphenylzirconium(IV) chloride

Guidance literature:: In dichloromethane-d2; (N2); drybox or Schlenk technique; CD2Cl2 was vac. transferred to mixt. of Zr complex and B compd. at -78°C; vigorously agitated at 23°C; NMR monitoring; not isolated;
DOI:10.1021/om700436z

Reference yield:

: 1291-32-3
zirconocene dichloride

: 591-51-5
phenyllithium

: 75061-73-3
dicyclopentadienylphenylzirconium(IV) chloride

Guidance literature:: In tetrahydrofuran-d8;
DOI:10.1016/j.tetlet.2014.01.080

Reference yield: 92.0%

: 17739-11-6
2-chloro-1,3-dimethyl-[1,3,2]diazaborolidine

: 76-09-5
2,3-dimethyl-2,3-butane diol

: 1942-45-6
4-Octyne

: 75061-73-3
dicyclopentadienylphenylzirconium(IV) chloride

: 1093343-35-1
(E)-4-phenyl-5-(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-4-octene

Guidance literature:: With toluene-4-sulfonic acid; In tetrahydrofuran; toluene; under N2; soln. of chloroborane, alkyne, and Zr complex in toluene addedto mixt. of Pd complex/P-ligand in toluene, mixt. heated at 120° C for 12 h, evapn. under vac.; pinacol, THF, and TsOH added to residue, mixt. stirred at room temp. for 3 h; soln. filtered through Florisil, filtrate evapd. under vac., column chromy. (SiO2, hexane/ethyl acetate (20/1));
DOI:10.1039/b809433k