5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Base Information

Chemical Name:5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde
CAS No.:289059-04-7
Molecular Formula:C₃₀H₂₃NO₂
Molecular Weight:429.518
Hs Code.:

Synonyms:5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Suppliers and Price of 5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of 5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Chemical Property:

Purity/Quality:: 98% ^*data from raw suppliers

Safty Information:

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Technology Process of 5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

There total 5 articles about 5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 56.0%

: 118-92-3,159201-01-1,50816-84-7,80206-34-4,104809-47-4
anthranilic acid

: 289059-03-6
5-[2-(acetylamino)anthracen-9-yl]-2-methylbenzaldehyde

: 289059-04-7
5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Guidance literature:: anthranilic acid; With isopentyl nitrite; trichloroacetic acid; In 1,4-dioxane; at 20 ℃; for 1h;

5-[2-(acetylamino)anthracen-9-yl]-2-methylbenzaldehyde; In 1,4-dioxane; for 1h; Heating;
DOI:10.1021/ja001048f

Reference yield:

: 613-13-8
2-aminoanthracene

: 289059-04-7
5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1.1: 83 percent / benzene / 12 h / Heating

2.1: 97 percent / Br₂ / CH₂Cl₂ / 0 °C

3.1: MeLi; n-BuLi / tetrahydrofuran; hexane; diethyl ether / -78 °C

3.2: tetrahydrofuran; diethyl ether; hexane / 2 h / -78 °C

3.3: 64 percent / H₂O / tetrahydrofuran; hexane; diethyl ether / -78 °C

4.1: 84 percent / 2 M aq. Na₂CO₃; Pd(PPh₃)4 / ethanol; toluene / 12 h / Heating

5.1: isoamyl nitrite; CCl₃CO₂H / dioxane / 1 h / 20 °C

5.2: 56 percent / dioxane / 1 h / Heating

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; methyllithium; bromine; sodium carbonate; isopentyl nitrite; trichloroacetic acid; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; hexane; dichloromethane; toluene; benzene; 1.1: Acetylation / 2.1: Bromination / 3.1: Metallation / 4.1: Suzuki coupling / 5.1: Diazotization / 5.2: Diels-Alder addition;
DOI:10.1021/ja001048f

Reference yield:

: 36761-80-5
2-(acetylamino)anthracene

: 289059-04-7
5-[2-(acetylamino)-9,10[1',2']-benzenoanthracen-9(10H)-yl]-2-methylbenzaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: 97 percent / Br₂ / CH₂Cl₂ / 0 °C

2.1: MeLi; n-BuLi / tetrahydrofuran; hexane; diethyl ether / -78 °C

2.2: tetrahydrofuran; diethyl ether; hexane / 2 h / -78 °C

2.3: 64 percent / H₂O / tetrahydrofuran; hexane; diethyl ether / -78 °C

3.1: 84 percent / 2 M aq. Na₂CO₃; Pd(PPh₃)4 / ethanol; toluene / 12 h / Heating

4.1: isoamyl nitrite; CCl₃CO₂H / dioxane / 1 h / 20 °C

4.2: 56 percent / dioxane / 1 h / Heating

With tetrakis(triphenylphosphine) palladium⁽⁰⁾; n-butyllithium; methyllithium; bromine; sodium carbonate; isopentyl nitrite; trichloroacetic acid; In tetrahydrofuran; 1,4-dioxane; diethyl ether; ethanol; hexane; dichloromethane; toluene; 1.1: Bromination / 2.1: Metallation / 3.1: Suzuki coupling / 4.1: Diazotization / 4.2: Diels-Alder addition;
DOI:10.1021/ja001048f