36761-80-5Relevant articles and documents
Aerobic C-H Oxidation of Arenes Using a Recyclable, Heterogeneous Rhodium Catalyst
Matsumoto, Kenji,Tachikawa, Shohei,Hashimoto, Noriko,Nakano, Rina,Yoshida, Masahiro,Shindo, Mitsuru
, p. 4305 - 4316 (2017)
A novel, practical protocol for the aerobic direct C-H acetoxylation of arenes, employing a recyclable heterogeneous rhodium catalyst, is reported herein. The trifluoroacetoxylation of 2-amido-substituted anthracenes proceeded at the 9-position with exclusive regioselectivity. The oxidation of variously substituted anthracenes and other polycyclic aromatics with molecular oxygen as a terminal oxidant proceeded under mild conditions, providing products in good to excellent yields.
Nickel-catalyzed reductive and borylative cleavage of aromatic carbon-nitrogen bonds in N-aryl amides and carbamates
Tobisu, Mamoru,Nakamura, Keisuke,Chatani, Naoto
supporting information, p. 5587 - 5590 (2014/05/06)
The nickel-catalyzed reaction of N-aryl amides with hydroborane or diboron reagents resulted in the formation of the corresponding reduction or borylation products, respectively. Mechanistic studies revealed that these reactions proceeded via the activation of the C(aryl)-N bonds of simple, electronically neutral substrates and did not require the presence of an ortho directing group.
1, 2-dihydro-3H-dibenzisoquinoline-1,3-dione anticancer agents
-
, (2008/06/13)
This invention relates to a compound useful for the treatment of tumors having the formula: STR1