((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

Base Information

Chemical Name:((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate
CAS No.:1206481-31-3
Molecular Formula:C₃₅H₅₄O₇Si
Molecular Weight:614.895
Hs Code.:

Synonyms:((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

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Chemical Property of ((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

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Technology Process of ((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

There total 1 articles about ((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: 1206481-30-2
((2S,4R,5S,6S)-6-((R,E)-4-(tert-butyldimethylsilyloxy)-pent-1-enyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

: 1206481-31-3
((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

Guidance literature:: With palladium 10% on activated carbon; hydrogen; In ethyl acetate; at 20 ℃; for 5h;
DOI:10.1016/j.tet.2009.11.024

Reference yield: 81.0%

: 1206481-31-3
((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate

: 1206481-32-4
((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methanol

Guidance literature:: ((2S,4R,5S,6S)-6-((R)-4-(tert-butyldimethylsilyloxy)-pentyl)-5-(4-methoxybenzyloxy)-2-phenyl-1,3-dioxan-4-yl)methyl pivalate; With diisobutylaluminium hydride; In hexane; dichloromethane; at -80 ℃; for 2h; Inert atmosphere;

With water; ammonium chloride; In hexane; dichloromethane; at -80 - 20 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2009.11.024