4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

Base Information

Chemical Name:4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde
CAS No.:1048039-36-6
Molecular Formula:C₂₃H₃₀O₂Si
Molecular Weight:366.576
Hs Code.:

Synonyms:4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

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Chemical Property of 4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

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Technology Process of 4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

There total 6 articles about 4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 51.0%

: 4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzonitrile

: 1048039-36-6
4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

Guidance literature:: With diisobutylaluminium hydride; In diethyl ether; at -78 - 20 ℃;
DOI:10.1021/ja049325w

Reference yield:

: 1552-41-6
diethyl [(4-cyanophenyl)methyl]phosphonate

: 1048039-36-6
4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

Guidance literature:: Multi-step reaction with 2 steps

1.1: LDA / tetrahydrofuran / 0.5 h / -78 °C

1.2: 80 percent / tetrahydrofuran / -78 - 20 °C

2.1: 51 percent / diisobutylaluminum hydride / diethyl ether / -78 - 20 °C

With diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; 1.2: Horner-Emmons reaction;
DOI:10.1021/ja049325w

Reference yield:

: 67373-56-2
chlorodimethyl(1,1,2-trimethylpropyl)silane

: 1048039-36-6
4-(2-{4-[dimethyl-(1,1,2-trimethylpropyl)silanyloxy]phenyl}vinyl)benzaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1.1: 85 percent / imidazole / CH₂Cl₂ / 5 h / 20 °C

2.1: LDA / tetrahydrofuran / 0.5 h / -78 °C

2.2: 80 percent / tetrahydrofuran / -78 - 20 °C

3.1: 51 percent / diisobutylaluminum hydride / diethyl ether / -78 - 20 °C

With 1H-imidazole; diisobutylaluminium hydride; lithium diisopropyl amide; In tetrahydrofuran; diethyl ether; dichloromethane; 2.2: Horner-Emmons reaction;
DOI:10.1021/ja049325w