6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

Base Information

Chemical Name:6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde
CAS No.:144801-93-4
Molecular Formula:C₄₁H₃₈O₃Si
Molecular Weight:606.836
Hs Code.:

Synonyms:6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

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Chemical Property of 6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

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Technology Process of 6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

There total 6 articles about 6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 92.0%

: 145127-73-7
[6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalen-2-yl]-methanol

: 144801-93-4
6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

Guidance literature:: With molecular sieve; pyridinium chlorochromate; In dichloromethane; for 1h; Ambient temperature;
DOI:10.1021/jm960301c

Reference yield:

: 81418-49-7
5-(benzyloxy)-2-bromobenzaldehyde dimethylacetal

: 144801-93-4
6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) n-BuLi / 1.) THF, hexane, -70 deg C, 15 min, 2.) THF, hexane, from -70 to 10 deg C

2: camphorsulfonic acid / toluene / 24 h / Heating

3: 29 percent / LiAlH₄ / tetrahydrofuran / 2.5 h / Heating

4: 73 percent / imidazole / tetrahydrofuran / 1 h / Ambient temperature

5: 92 percent / pyridinium chlorochromate, molecular sieves / CH₂Cl₂ / 1 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; molecular sieve; camphor-10-sulfonic acid; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/jm960301c

Reference yield:

: 100-52-7
benzaldehyde

: 144801-93-4
6-Benzyloxy-3-(tert-butyl-diphenyl-silanyloxymethyl)-1-phenyl-naphthalene-2-carbaldehyde

Guidance literature:: Multi-step reaction with 5 steps

1: 1.) n-BuLi / 1.) THF, hexane, -70 deg C, 15 min, 2.) THF, hexane, from -70 to 10 deg C

2: camphorsulfonic acid / toluene / 24 h / Heating

3: 29 percent / LiAlH₄ / tetrahydrofuran / 2.5 h / Heating

4: 73 percent / imidazole / tetrahydrofuran / 1 h / Ambient temperature

5: 92 percent / pyridinium chlorochromate, molecular sieves / CH₂Cl₂ / 1 h / Ambient temperature

With 1H-imidazole; lithium aluminium tetrahydride; n-butyllithium; molecular sieve; camphor-10-sulfonic acid; pyridinium chlorochromate; In tetrahydrofuran; dichloromethane; toluene;
DOI:10.1021/jm960301c