1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone

Base Information

• Chemical Name: 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone
• CAS No.: 357396-88-4
• Molecular Formula: C₄₂H₆₀I₂N₂O₆S
• Molecular Weight: 974.823
• Mol file: 357396-88-4.mol

Synonyms:1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone

Chemical Property of 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone

There total 8 articles about 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

1-(3,4-dihexyloxyphenyl)-5-bromo-pentan-1-one (357396-85-1) → 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone (357396-88-4)

Guidance literature:

Multi-step reaction with 2 steps

1: 93 percent / potassium carbonate / various solvent(s) / 16 h / Heating

2: ethanol / 3 h / Heating

With potassium carbonate; In ethanol;

DOI:10.1021/ja015614y

Reference yield:

1-bromo-hexane (111-25-1) → 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone (357396-88-4)

Guidance literature:

Multi-step reaction with 4 steps

1: 91 percent / KOH

2: 88 percent / AlCl₃ / CS₂ / 0 - 40 °C

3: 93 percent / potassium carbonate / various solvent(s) / 16 h / Heating

4: ethanol / 3 h / Heating

With potassium hydroxide; aluminium trichloride; potassium carbonate; In carbon disulfide; ethanol; 2: Friedel-Crafts acylation;

DOI:10.1021/ja015614y

Reference yield:

1,2-dihexyloxybenzene (94259-20-8) → 1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on para-tosyl hydrazone (357396-88-4)

Guidance literature:

Multi-step reaction with 3 steps

1: 88 percent / AlCl₃ / CS₂ / 0 - 40 °C

2: 93 percent / potassium carbonate / various solvent(s) / 16 h / Heating

3: ethanol / 3 h / Heating

With aluminium trichloride; potassium carbonate; In carbon disulfide; ethanol; 1: Friedel-Crafts acylation;

DOI:10.1021/ja015614y

upstream raw materials:

1-(3,4-bis-hexyloxy-phenyl)-5-(4-hexyloxy-2,5-diiodo-phenoxy)-pentane-1-on

toluene-4-sulfonic acid hydrazide

1-(3,4-dihexyloxyphenyl)-5-bromo-pentan-1-one

1-bromo-hexane

Downstream raw materials:

C₉₅H₅₂I₂O₄