(S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

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Chemical Name:(S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide
CAS No.:1221678-59-6
Molecular Formula:C₁₉H₂₅NO₅
Molecular Weight:347.411
Hs Code.:

Synonyms:(S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

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Chemical Property of (S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

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Technology Process of (S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

There total 2 articles about (S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 82.0%

: 1202776-27-9
C₁₉H₂₇NO₅

: 1221678-59-6
(S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

Guidance literature:: With manganese(IV) oxide; In dichloromethane; at 0 ℃; for 6h; Inert atmosphere;
DOI:10.1016/j.tet.2012.05.126

Reference yield: 76.0%

: C₁₉H₂₇NO₅

: 1221678-59-6
(S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

Guidance literature:: With manganese(IV) oxide; In dichloromethane; at 0 ℃; for 8h;
DOI:10.1016/j.tetlet.2009.10.023

Reference yield: 91.0%

: 1221678-59-6
(S,Z)-N-benzylidene-1-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro-[3,4-d][1,3]dioxol-4-yl)but-3-en-1-amine oxide

: 1202776-29-1
(2S,4R,6R)-2-((3aR,4R,6R,6aR)-6-methoxy-2,2-dimethyltetrahydrofuro[3,4-d][1,3]dioxol-4-yl)-6-phenyl-7-oxa-1-azabicyclo[2.2.1]heptane

Guidance literature:: In toluene; at 100 ℃; for 72h; optical yield given as %de; diastereoselective reaction; Sealed vessel;
DOI:10.1016/j.tet.2012.05.126