4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

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Chemical Name:4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one
CAS No.:155434-92-7
Molecular Formula:C₅₆H₆₆N₄O₂₀
Molecular Weight:1115.15
Hs Code.:

4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

Synonyms:4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

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Chemical Property of 4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

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Technology Process of 4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

There total 19 articles about 4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 73.0%

: 104705-82-0
methyl 2-acetoxymethyl-5-formyl-4-(methoxycarbonylmethylpyrrole)-3-propionate

: 155434-91-6
4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-2,7-bis-(2-methoxycarbonylethyl)-3,8-bis(methoxycarbonylmethyl)-4,5-dihydrodipyrrin-1(10H)-one

: 155434-92-7
4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

Guidance literature:: With tin(IV) chloride; In tetrahydrofuran; dichloromethane; for 18h;

Reference yield:

: 50622-78-1
Benzyl 4-(2-methoxycarbonylethyl)-3-methoxycarbonylmethyl-5-methylpyrrole-2-carboxylate

: 155434-92-7
4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

Guidance literature:: Multi-step reaction with 9 steps

1: 90 percent / H₂ / Pd-on-charcoal / methanol / 4 h / Ambient temperature

2: oxalyl chloride / CH₂Cl₂ / 0.5 h

3: N,N-dimethylaniline / CH₂Cl₂ / 1.) room temperature, 30 min, 2.) reflux, 10 min

4: SO₂Cl₂ / CH₂Cl₂ / 0.25 h

5: AcONa / 1 h / 75 °C

6: 1.) stannic chloride, 2.) p-TsOH*H₂O, AgOAc / 1.) CH₂Cl₂, 0 deg C, 20 min, 2.) THF, room temperature, 12 h

7: AcOH, Zn / 0.33 h

8: trifluoroacetic acid / 7 h / Ambient temperature

9: 73 percent / stannic chloride / CH₂Cl₂; tetrahydrofuran / 18 h

With sulfuryl dichloride; oxalyl dichloride; hydrogen; silver(I) acetate; sodium acetate; tin(IV) chloride; toluene-4-sulfonic acid; acetic acid; N,N-dimethyl-aniline; trifluoroacetic acid; zinc; palladium on activated charcoal; In tetrahydrofuran; methanol; dichloromethane;

Reference yield:

: 155434-89-2
4-[5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl]-2,7-bis-(2-methoxycarbonylethyl)-3,8-bis(methoxycarbonylmethyl)-9-(2,2,2-tribromoethoxycarbonyl)-4,5-dihydrodipyrrin-1(10H)-one

: 155434-92-7
4-<5-benzyloxycarbonyl-4-(2-methoxycarbonylethyl)-3-(methoxycarbonylmethyl)pyrrol-2-ylmethyl>-14-formyl-2,7,12-tris(2-methoxycarbonylethyl)-3,8,13.tris(methoxycarbonylmethyl)-4,5,10,16-tetrahydrotripyrrin-2(15H)-one

Guidance literature:: Multi-step reaction with 3 steps

1: AcOH, Zn / 0.33 h

2: trifluoroacetic acid / 7 h / Ambient temperature

3: 73 percent / stannic chloride / CH₂Cl₂; tetrahydrofuran / 18 h

With tin(IV) chloride; acetic acid; trifluoroacetic acid; zinc; In tetrahydrofuran; dichloromethane;