tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

Base Information

Chemical Name:tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane
CAS No.:1381848-59-4
Molecular Formula:C₂₆H₄₆O₅Si
Molecular Weight:466.734
Hs Code.:

Synonyms:tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

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Chemical Property of tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

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Technology Process of tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

There total 6 articles about tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 1381848-58-3
tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

: 1381848-59-4
tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

Guidance literature:: With camphor-10-sulfonic acid; In methanol; dichloromethane; at 0 ℃; for 2.41667h;
DOI:10.1021/acs.joc.7b02293

Reference yield:

: C₁₈H₂₈O₃Si

: 1381848-59-4
tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

Guidance literature:: Multi-step reaction with 5 steps

1.1: CrCl(C₆H₂(O)(C₁₀H₁₅)(CH₃)(CHNC₉H₈O)) / 20.5 h / 20 °C / Molecular sieve

2.1: potassium carbonate / methanol / 0.5 h / 20 °C

2.2: 20 °C

3.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.67 h / -20 °C

4.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C

5.1: camphor-10-sulfonic acid / methanol; dichloromethane / 1 h / 0 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; CrCl(C₆H₂(O)(C₁₀H₁₅)(CH₃)(CHNC₉H₈O)); cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; potassium carbonate; In methanol; dichloromethane;
DOI:10.1021/ol301278e

Reference yield:

: 1381848-54-9
C₂₆H₄₆O₅Si₂

: 1381848-59-4
tert-butyl(((2S,4S,5S,6S)-6-(2-((4-methoxybenzyl)oxy)ethyl)-5-methyl-4-((triisopropylsilyl)oxy)tetrahydro-2H-pyran-2-yl)methoxy)dimethylsilane

Guidance literature:: Multi-step reaction with 4 steps

1.1: potassium carbonate / methanol / 0.5 h / 20 °C

1.2: 20 °C

2.1: sodium tetrahydroborate; cerium(III) chloride heptahydrate / methanol / 0.67 h / -20 °C

3.1: 2,6-dimethylpyridine / dichloromethane / 1 h / 0 °C

4.1: camphor-10-sulfonic acid / methanol; dichloromethane / 1 h / 0 °C

With 2,6-dimethylpyridine; sodium tetrahydroborate; cerium(III) chloride heptahydrate; camphor-10-sulfonic acid; potassium carbonate; In methanol; dichloromethane;
DOI:10.1021/ol301278e