1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

Base Information

Chemical Name:1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde
CAS No.:430436-63-8
Molecular Formula:C₃₅H₅₄O₄Si₃
Molecular Weight:623.068
Hs Code.:

Synonyms:1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

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Chemical Property of 1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

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Technology Process of 1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

There total 5 articles about 1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 430436-62-7
1,3-bis(tert-butyldimethylsilanyloxy)-6H-5-oxa-benzo[c]phenanthren-6-ol

: 430436-63-8
1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

Guidance literature:: 1,3-bis(tert-butyldimethylsilanyloxy)-6H-5-oxa-benzo[c]phenanthren-6-ol; With potassium tert-butylate; In tetrahydrofuran; at 0 ℃; for 0.0833333h;

tert-butyldimethylsilyl chloride; In tetrahydrofuran; at 0 - 20 ℃; Further stages.;
DOI:10.1021/ja0171198

Reference yield:

: 18162-48-6
tert-butyldimethylsilyl chloride

: 430436-63-8
1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

Guidance literature:: Multi-step reaction with 3 steps

1.1: imidazole / dimethylformamide / 1 h / 60 °C

2.1: 57 percent / lithium diisobutylaluminumhydride / tetrahydrofuran / 3 °C

3.1: t-BuOK / tetrahydrofuran / 0.08 h / 0 °C

3.2: tetrahydrofuran / 0 - 20 °C

With 1H-imidazole; lithium diisobutylaluminium hydride; potassium tert-butylate; In tetrahydrofuran; N,N-dimethyl-formamide;
DOI:10.1021/ja0171198

Reference yield:

: 138435-70-8
1,3-dimethoxy-6H-benzo[b]naphto[1,2-d]pyranone

: 430436-63-8
1-[2,4,6-tris(tert-butyldimethylsilanyloxy)phenyl]naphthalene-2-carbaldehyde

Guidance literature:: Multi-step reaction with 4 steps

1.1: 54 percent / BBr₃ / 1,2-dichloro-ethane / 8 h / 70 °C

2.1: imidazole / dimethylformamide / 1 h / 60 °C

3.1: 57 percent / lithium diisobutylaluminumhydride / tetrahydrofuran / 3 °C

4.1: t-BuOK / tetrahydrofuran / 0.08 h / 0 °C

4.2: tetrahydrofuran / 0 - 20 °C

With 1H-imidazole; lithium diisobutylaluminium hydride; potassium tert-butylate; boron tribromide; In tetrahydrofuran; 1,2-dichloro-ethane; N,N-dimethyl-formamide;
DOI:10.1021/ja0171198