glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

Base Information

Chemical Name:glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester
CAS No.:945920-73-0
Molecular Formula:C₂₁H₂₂N₂O₁₀
Molecular Weight:464.397
Hs Code.:

Synonyms:glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

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Chemical Property of glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

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Technology Process of glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

There total 3 articles about glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 69.0%

: 80404-34-8
α,α-dideuterio-2-nitrobenzyl alcohol

: 457612-05-4
glutaric acid mono-(4,5-dimethoxy-2-nitrobenzyl) ester

: 945920-73-0
glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

Guidance literature:: With dmap; dicyclohexyl-carbodiimide; In chloroform; at 60 ℃; for 24h;
DOI:10.1021/ol070820h

Reference yield:

: 552-16-9,104810-18-6
ortho-nitrobenzoic acid

: 945920-73-0
glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

Guidance literature:: Multi-step reaction with 3 steps

1.1: 100 percent / thionyl chloride / toluene / 3 h / Heating

2.1: NaBD₄ / dimethylformamide; tetrahydrofuran / 24 h / 20 °C

2.2: 94 percent / aq. HCl / dimethylformamide; tetrahydrofuran

3.1: 69 percent / 4-N,N-dimethylaminopyridine; N,N'-dicyclohexylcarbodiimide / CHCl₃ / 24 h / 60 °C

With dmap; thionyl chloride; sodium borodeuteride; dicyclohexyl-carbodiimide; In tetrahydrofuran; chloroform; N,N-dimethyl-formamide; toluene;
DOI:10.1021/ol070820h

Reference yield:

: 610-14-0
2-nitrobenzyl chloride

: 945920-73-0
glutaric acid (4,5-dimethoxy-2-nitrobenzyl) ester (α,α-dideuterio-2-nitrobenzyl) ester

Guidance literature:: Multi-step reaction with 2 steps

1.1: NaBD₄ / dimethylformamide; tetrahydrofuran / 24 h / 20 °C

1.2: 94 percent / aq. HCl / dimethylformamide; tetrahydrofuran

2.1: 69 percent / 4-N,N-dimethylaminopyridine; N,N'-dicyclohexylcarbodiimide / CHCl₃ / 24 h / 60 °C

With dmap; sodium borodeuteride; dicyclohexyl-carbodiimide; In tetrahydrofuran; chloroform; N,N-dimethyl-formamide;
DOI:10.1021/ol070820h