4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))

Base Information

• Chemical Name: 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))
• CAS No.: 1392231-59-2
• Molecular Formula: C₅₂H₆₈I₂N₆Rh₂
• Molecular Weight: 1236.77

Synonyms:4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))

Chemical Property of 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))

Chemical Property:

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Technology Process of 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I))

There total 2 articles about 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η²:η²-cycloocta-1,5-diene)iodidorhodium(I)) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 83.0%

methoxy(cyclooctadiene)rhodium(I) dimer + 4,4′-(1,3-phenylene)bis(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium) trifluoromethanesulfonate → 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η2:η2-cycloocta-1,5-diene)iodidorhodium(I)) (1392231-59-2)

Guidance literature:

With potassium iodide; In acetonitrile; at 80 ℃; for 1h; Inert atmosphere; Sealed tube;

DOI:10.1021/om300423z

Reference yield:

methoxy(cyclooctadiene)rhodium(I) dimer + (1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-4-yl)phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η2:η2-cycloocta-1,5-iene)iodidorhodium(I) iodide (1392231-64-9) → 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η2:η2-cycloocta-1,5-diene)iodidorhodium(I)) (1392231-59-2)

Guidance literature:

With potassium iodide; In acetonitrile; at 80 ℃; Inert atmosphere; Sealed tube;

DOI:10.1021/om300423z

Reference yield: 78.0%

carbon monoxide (201230-82-2) + 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)(η2:η2-cycloocta-1,5-diene)iodidorhodium(I)) (1392231-59-2) → 4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)dicarbonyliodidorhodium(I)) (1392231-62-7)

Guidance literature:

In acetonitrile; at 20 ℃; for 0.25h; Inert atmosphere;

DOI:10.1021/om300423z

upstream raw materials:

(1-(2,6-diisopropylphenyl)-4-(3-(1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-3-ium-4-yl)phenyl)-3-methyl-1H-1,2,3-triazol-3-ium-5-yl)(η²:η²-cycloocta-1,5-iene)iodidorhodium(I) iodide

Downstream raw materials:

4,4′-(1,3-phenylene)bis((1-(2,6-diisopropylphenyl)-3-methyl-1H-1,2,3-triazol-5-yl)dicarbonyliodidorhodium(I))

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