bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

Base Information

Chemical Name:bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)
CAS No.:155917-19-4
Molecular Formula:C₃₇H₅₅NOP₂Ru
Molecular Weight:692.867
Hs Code.:

Synonyms:bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

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Chemical Property of bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

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Technology Process of bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

There total 1 articles about bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 98.0%

: {(carbonyl)(PhCC)bis(triisopropylphosphine)}ruthenium(II)

: 155917-19-4
bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

Guidance literature:: With CH₃CN; In acetonitrile; under Ar, standard Schlenk techniques; treating Ru-compd. with acetonitrile; filtering off the ppt., washing with CH3CN and drying in vac.; elem. anal.;
DOI:10.1021/om00017a026

Reference yield: 64.0%

: tetrafluoroboric acid

: 155917-19-4
bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

: 155917-21-8
(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

Guidance literature:: With CH₃CN; In diethyl ether; acetonitrile; byproducts: (C6H5)CCH; under Ar, standard Schlenk techniques; treating a suspension of Ru-compd. in CH3CN with an Et2O soln. of HBF4, stirring for 10 min at room temp.; pptn. by concg. and addn. of Et2O, filtering off the ppt., washing withEt2O and drying in vac.; elem. anal.;
DOI:10.1021/om00017a026

Reference yield:

: 155917-19-4
bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

: 155917-31-0
((phenyl)vinylacetato)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

Guidance literature:: Multi-step reaction with 2 steps

1: CH₃CN / diethyl ether; acetonitrile

2: CH₃COOH / acetone

With CH₃CN; CH₃COOH; In diethyl ether; acetone; acetonitrile;
DOI:10.1021/om00017a026