(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

Base Information

Chemical Name:(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate
CAS No.:155917-21-8
Molecular Formula:BF₄*C₃₁H₅₃N₂OP₂Ru
Molecular Weight:719.597
Hs Code.:

Synonyms:(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

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Chemical Property of (phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

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Technology Process of (phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

There total 2 articles about (phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 64.0%

: tetrafluoroboric acid

: 155917-19-4
bis(phenylethynyl)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II)

: 155917-21-8
(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

Guidance literature:: With CH₃CN; In diethyl ether; acetonitrile; byproducts: (C6H5)CCH; under Ar, standard Schlenk techniques; treating a suspension of Ru-compd. in CH3CN with an Et2O soln. of HBF4, stirring for 10 min at room temp.; pptn. by concg. and addn. of Et2O, filtering off the ppt., washing withEt2O and drying in vac.; elem. anal.;
DOI:10.1021/om00017a026

Reference yield:

: {(carbonyl)(PhCC)bis(triisopropylphosphine)}ruthenium(II)

: 155917-21-8
(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

Guidance literature:: Multi-step reaction with 2 steps

1: CH₃CN / acetonitrile

2: CH₃CN / diethyl ether; acetonitrile

With CH₃CN; In diethyl ether; acetonitrile;
DOI:10.1021/om00017a026

Reference yield: 61.0%

: 155917-21-8
(phenylethynyl)(carbonyl)(acetonitrile)2bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

: 155917-31-0
((phenyl)vinylacetato)(carbonyl)(acetonitrile)bis(triisopropylphosphine)ruthenium(II) tetrafluoroborate

Guidance literature:: With CH₃COOH; In acetone; byproducts: CH3CN; under Ar, standard Schlenk techniques; treating a soln. of Ru-compd. inacetone with glacial acetic acid, stirring for 24 h at room temp.; pptn. by concg. and addn. of Et2O, filtering off ppt., washing with Et2O and drying in vac.; elem. anal.;
DOI:10.1021/om00017a026