4,6-O-Isopropylidene-D-glucal

Base Information

Chemical Name:4,6-O-Isopropylidene-D-glucal
CAS No.:51450-36-3
Molecular Formula:C₉H₁₄O₄
Molecular Weight:186.208
Hs Code.:
European Community (EC) Number:803-938-6
Nikkaji Number:J1.011.051C,J273.884H
Wikidata:Q76416543
Mol file:51450-36-3.mol

Synonyms:4,6-O-ISOPROPYLIDENE-D-GLUCAL;51450-36-3;(4aR,8R,8aS)-2,2-dimethyl-4,4a,8,8a-tetrahydropyrano[3,2-d][1,3]dioxin-8-ol;MFCD22988998;4,6-O-Isopropylidene-D-glucal, 97%;4-O,6-O-Isopropylidene-1,2-dideoxy-D-arabino-1-hexenopyranose;1,2-Didehydro-1,2-dideoxy-4-O,6-O-isopropylidene-beta-D-glucopyranose

Suppliers and Price of 4,6-O-Isopropylidene-D-glucal

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Sigma-Aldrich
4,6-O-Isopropylidene-D-glucal 97%
5g
$ 505.00

Sigma-Aldrich
4,6-O-Isopropylidene-D-glucal 97%
1g
$ 168.00

Crysdot
4,6-O-ISOPROPYLIDENE-D-GLUCAL 95+%
5g
$ 805.00

Alfa Aesar
4,6-O-Isopropylidene-D-glucal, 97%
1g
$ 138.00

Alfa Aesar
4,6-O-Isopropylidene-D-glucal, 97%
250mg
$ 40.70

Total 6 raw suppliers

Chemical Property of 4,6-O-Isopropylidene-D-glucal

Chemical Property:

Refractive Index:n20/D1.487
Boiling Point:306.8±42.0 °C(Predicted)
PKA:12?+-.0.40(Predicted)
Flash Point:>110℃
Density:1.179 g/mL at 25 °C
Storage Temp.:2-8°C
XLogP3:0
Hydrogen Bond Donor Count:1
Hydrogen Bond Acceptor Count:4
Rotatable Bond Count:0
Exact Mass:186.08920892
Heavy Atom Count:13
Complexity:224

Purity/Quality:

99% ^*data from raw suppliers

4,6-O-Isopropylidene-D-glucal 97% ^*data from reagent suppliers

Safty Information:

Pictogram(s):
Hazard Codes:Xi
Statements: 36
Safety Statements: 26

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC1(OCC2C(O1)C(C=CO2)O)C
Isomeric SMILES:CC1(OC[C@@H]2[C@@H](O1)[C@@H](C=CO2)O)C
Uses 4,6-O-Isopropylidene-D-glucal is used as pharmaceutical intermediate.

Technology Process of 4,6-O-Isopropylidene-D-glucal

There total 15 articles about 4,6-O-Isopropylidene-D-glucal which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 345197-64-0
1-phenylthio-1-deoxy-2,3,4,6-di-(O-isopropylidene)-β-D-glucopyranoside

: 51450-36-3
4,6-O-isopropylidene-D-glucal

Guidance literature:: 1-phenylthio-1-deoxy-2,3,4,6-di-(O-isopropylidene)-β-D-glucopyranoside; With naphthalene; lithium; In tetrahydrofuran; at -72 ℃; for 0.666667h; Inert atmosphere;

With water; In tetrahydrofuran; at -72 ℃; Inert atmosphere;
DOI:10.1016/j.tet.2010.03.093

Reference yield: 90.0%

: 224778-46-5
2,3:4,6-di-O-isopropylidenemannopyranosyl bromide

: 51450-36-3
4,6-O-isopropylidene-D-glucal

Guidance literature:: With bis(cyclopentadienyl)-titanium(III) chloride; In benzene; for 0.5h; Ambient temperature;
DOI:10.1021/jo982447k

Reference yield: 88.0%

: 1071917-37-7
C₁₈H₂₄O₆S

: 51450-36-3
4,6-O-isopropylidene-D-glucal

Guidance literature:: With tert.-butyl lithium; In tetrahydrofuran; at -78 ℃; for 0.5h; Reagent/catalyst; Reactivity; Inert atmosphere;
DOI:10.1002/ejoc.200800318