((Phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

Base Information

Chemical Name:((Phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)
CAS No.:53103-03-0
Molecular Formula:C₄₂H₃₃P₃
Molecular Weight:630.645
Hs Code.:
European Community (EC) Number:962-373-4
Nikkaji Number:J951.399J

Synonyms:((phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane);SCHEMBL8073956;bis-(o-diphenylphosphinophenyl)phenylphosphine;53103-03-0

Suppliers and Price of ((Phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of ((Phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

Chemical Property:

XLogP3:10
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:0
Rotatable Bond Count:9
Exact Mass:630.17951205
Heavy Atom Count:45
Complexity:733

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Canonical SMILES:C1=CC=C(C=C1)P(C2=CC=CC=C2)C3=CC=CC=C3P(C4=CC=CC=C4)C5=CC=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7

Technology Process of ((Phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

There total 1 articles about ((Phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 86.0%

: 644-97-3
Dichlorophenylphosphine

: 62336-24-7
(2-bromophenyl)diphenylphosphane

: 53103-03-0
((phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

Guidance literature:: (2-bromophenyl)diphenylphosphane; With n-butyllithium; In tetrahydrofuran; at -78 ℃; for 1h;

Dichlorophenylphosphine; In tetrahydrofuran; at -70 - 20 ℃; for 4h;
DOI:10.1021/acs.inorgchem.5b02581

Reference yield: 87.0%

: WCl₄(P(C₆H₅)3)2*CH₂Cl₂

: 53103-03-0
((phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

: W⁽⁴⁺⁾*4Cl^(1-)*C₆H₅P(C₆H₄P(C₆H₅)2)2=WCl₄(C₆H₅P(C₆H₄P(C₆H₅)2)2)

Guidance literature:: In benzene; under dry Ar, Schlenk techniques; addn. of phosphine to suspn. of W-complex in benzene, mixt. refluxed (3 h),; evapn., soln. of residue in CH2Cl2, addn. of ether, pptn., filtration, washed (ether, three times), dried in vacuo; elem. anal.;

Reference yield: 87.0%

: 586959-39-9
gold(I) cyanide

: 53103-03-0
((phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane)

: 2923-28-6
silver trifluoromethanesulfonate

: [Ag(bis(o-diphenylphosphinophenyl)phenylphosphine)CNAu(bis(2-diphenylphosphinophenyl)phenylphosphine)]*(CF₃SO₃)

Guidance literature:: gold(I) cyanide; ((phenylphosphanediyl)bis(2,1-phenylene))bis(diphenylphosphane); In dichloromethane; at 20 ℃; for 1h;

silver trifluoromethanesulfonate; In dichloromethane; acetone; for 10h;
DOI:10.1021/acs.inorgchem.5b02581