(Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

Base Information

Chemical Name:(Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline
CAS No.:1017572-74-5
Molecular Formula:C₁₉H₂₀ClNOSi
Molecular Weight:341.912
Hs Code.:

Synonyms:(Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

Suppliers and Price of (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

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Technology Process of (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

There total 3 articles about (Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 44.0%

: 4018-82-0
4-chloro-N-(4-methoxyphenyl)benzamide

: 14630-40-1
Bis(trimethylsilyl)ethyne

: 1017572-74-5
(Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

Guidance literature:: With trifluoromethanesulfonic acid anhydride; Triphenylphosphine oxide; In dichloromethane; at 0 - 20 ℃; for 6h;
DOI:10.1016/j.tetlet.2008.01.024

Reference yield:

: C₁₄H₁₁Cl₂NO

: 1066-54-2
trimethylsilylacetylene

: 1017572-74-5
(Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

Guidance literature:: With palladium diacetate; triethylamine; triphenylphosphine; at 70 - 80 ℃; for 2h; Inert atmosphere;
DOI:10.1021/acs.joc.9b02364

Reference yield:

: 4018-82-0
4-chloro-N-(4-methoxyphenyl)benzamide

: 1017572-74-5
(Z)-N-(1-(4-chlorophenyl)-3-(trimethylsilyl)prop-2-ynylidene)-4-methoxyaniline

Guidance literature:: Multi-step reaction with 2 steps

1: thionyl chloride / 1.5 h / 75 - 80 °C / Inert atmosphere

2: palladium diacetate; triphenylphosphine; triethylamine / 2 h / 70 - 80 °C / Inert atmosphere

With thionyl chloride; palladium diacetate; triethylamine; triphenylphosphine;
DOI:10.1021/acs.joc.9b02364