benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate

Base Information

• Chemical Name: benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate
• CAS No.: 1146730-24-6
• Molecular Formula: C₁₆H₁₆O₆
• Molecular Weight: 304.299
• Mol file: 1146730-24-6.mol

Synonyms:benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate

Chemical Property of benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate

Chemical Property:

Purity/Quality:

Safty Information:

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MSDS Files:

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Technology Process of benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate

There total 1 articles about benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 36.0%

benzyl methyl succinate (119450-11-2) → dibenzyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate + benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate (1146730-24-6) + 1,4-cyclohexanedione-2,5-di-carboxylic acid methyl ester (27712-87-4)

Guidance literature:

With sodium hydride; In dimethyl sulfoxide; mineral oil; at 0 - 23 ℃; for 3.5h;

DOI:10.1002/chem.200802151

Reference yield: 84.0%

benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate (1146730-24-6) → 1-benzyl 4-methyl 2,5-diaminoterephthalate (1146730-26-8)

Guidance literature:

benzyl methyl 2,5-dihydroxycyclohexa-1,4-diene-1,4-dicarboxylate; With ammonia; In ethanol; at 60 ℃; for 1h;

With hydrogenchloride; In ethanol; at 60 ℃; for 72h;

DOI:10.1002/chem.200802151

upstream raw materials:

benzyl methyl succinate

Downstream raw materials:

1-benzyl 4-methyl 2,5-diaminoterephthalate