(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

Base Information

Chemical Name:(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate
CAS No.:1426828-71-8
Molecular Formula:C₆₈H₈₃N₃O₇S₂Si
Molecular Weight:1146.64
Hs Code.:

(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

Synonyms:(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

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Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

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Chemical Property of (3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

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Technology Process of (3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

There total 1 articles about (3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 99.0%

: 1426828-70-7
(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-(4-methoxybenzyloxy)-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanoate

: 1426828-71-8
(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

Guidance literature:: With 2,3-dicyano-5,6-dichloro-p-benzoquinone; In dichloromethane; water; at 20 ℃; for 3h;
DOI:10.1016/j.ejmech.2012.12.023

Reference yield: 99.0%

: 1426828-71-8
(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

: 1426828-63-8
(7S,11R,14S,17R,18S,E)-18-(tert-butyldimethylsilyloxy)-7-hydroxy-17-isobutyl-11-methyl-9,12,15-trioxo-1,1,1,-triphenyl-14-tritylthiomethyl-2-thia-10,13,16-triazaicos-5-en-20-oic acid

Guidance literature:: With morpholine; tetrakis(triphenylphosphine) palladium⁽⁰⁾; In tetrahydrofuran; at 20 ℃; for 0.5h; Inert atmosphere;
DOI:10.1016/j.ejmech.2012.12.023

Reference yield:

: 1426828-71-8
(3S,4R)-allyl 3-(tert-butyldimethylsiloxy)-4-{(S)-2-[(R)-2-[(S,E)-3-hydroxy-7-(tritylthio)hept-4-enoylamino]propionylamino]-3-tritylthio(propionylamino)}-6-methylheptanate

: 1426828-73-0
(2S,6R,9S,12R,13S)-13-(tert-butyldimethylsiloxy)-12-isobutyl-6-methyl-2-[(E)-4-(tritylthio)but-1-enyl]-9-tritylthiomethyl-1-oxa-5,8,11-triazacyclopentadecane-4,7,10,15-tetraone

Guidance literature:: Multi-step reaction with 2 steps

1: tetrakis(triphenylphosphine) palladium⁽⁰⁾; morpholine / tetrahydrofuran / 0.5 h / 20 °C / Inert atmosphere

2: dmap; 2-methyl-6-nitrobenzoic anhydride / dichloromethane / 20 °C

With morpholine; dmap; tetrakis(triphenylphosphine) palladium⁽⁰⁾; 2-methyl-6-nitrobenzoic anhydride; In tetrahydrofuran; dichloromethane;
DOI:10.1016/j.ejmech.2012.12.023