N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

Base Information

Chemical Name:N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester
CAS No.:117942-45-7
Molecular Formula:C₂₂H₃₅NO₇Si
Molecular Weight:453.608
Hs Code.:

Synonyms:N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

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Chemical Property of N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

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Technology Process of N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

There total 6 articles about N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 117942-42-4
diethyl 4-<(2-methoxyethoxy)methoxy>benzalmalonate

: 117942-45-7
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

Guidance literature:: Multi-step reaction with 4 steps

1: 76 percent / dimethylsulfoxide; tetrahydrofuran / 1.) RT, 1 h, 2.) 50 deg C, 1 h

2: 78 percent / NaOH, H₂O / ethanol / 48 h / Ambient temperature

3: DPPA, Et₂N / toluene / 1 h / Heating

4: toluene / 20 h

With sodium hydroxide; diphenyl-phosphinic acid; water; diethylamine; In tetrahydrofuran; ethanol; dimethyl sulfoxide; toluene;
DOI:10.1021/jo00262a033

Reference yield:

: 117942-44-6
(Z)-1-(ethoxycarbonyl)-2-<4-<(2-methoxyethoxy)methoxy>phenyl>cyclopropanecarboxylic acid

: 117942-45-7
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

Guidance literature:: Multi-step reaction with 2 steps

1: DPPA, Et₂N / toluene / 1 h / Heating

2: toluene / 20 h

With diphenyl-phosphinic acid; diethylamine; In toluene;
DOI:10.1021/jo00262a033

Reference yield:

: 117942-43-5
diethyl 2-<4-<(2-methoxyethoxy)methoxy>phenyl>cyclopropane-1,1-dicarboxylate

: 117942-45-7
N-<<2-(trimethylsilyl)ethoxy>carbonyl>-O-<(2-methoxyethoxy)methyl>-(E)-2,3-methanotyrosine ethyl ester

Guidance literature:: Multi-step reaction with 3 steps

1: 78 percent / NaOH, H₂O / ethanol / 48 h / Ambient temperature

2: DPPA, Et₂N / toluene / 1 h / Heating

3: toluene / 20 h

With sodium hydroxide; diphenyl-phosphinic acid; water; diethylamine; In ethanol; toluene;
DOI:10.1021/jo00262a033