Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

Base Information

Chemical Name:Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane
CAS No.:472986-73-5
Molecular Formula:C₂₁H₃₈O₂Si
Molecular Weight:350.617
Hs Code.:

Synonyms:Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

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Chemical Property of Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

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Technology Process of Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

There total 6 articles about Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 472986-72-4
1-((2S,3R)-3-Isobutyl-oxiranyl)-1-((1S,2R)-4-methyl-2-triethylsilanyloxy-cyclohex-3-enyl)-2-trimethylsilanyl-ethanol

: 472986-73-5
Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

Guidance literature:: With potassium hexamethylsilazane; In tetrahydrofuran; toluene; at 0 ℃; for 1.5h;
DOI:10.1021/jo0203140

Reference yield:

: 994-30-9
triethylsilyl chloride

: 472986-73-5
Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

Guidance literature:: Multi-step reaction with 5 steps

1.1: CeCl₃*7H₂O; NaBH₄ / methanol / 1 h / -78 - -18 °C

1.2: imidazole / dimethylformamide / 2 h / 0 °C

1.3: diisobutylaluminium hydride / CH₂Cl₂; toluene / 1.5 h / -78 °C

2.1: VO(acac)2; t-BuOOH / CH₂Cl₂; toluene / 2.5 h / 0 °C

3.1: Dess-Martin periodinane / CH₂Cl₂ / 1 h / 0 °C

4.1: tetrahydrofuran; diethyl ether / 1 h / 0 °C

5.1: potassium hexamethyldisilazide / tetrahydrofuran; toluene / 1.5 h / 0 °C

With tert.-butylhydroperoxide; sodium tetrahydroborate; cerium(III) chloride; bis(acetylacetonate)oxovanadium; potassium hexamethylsilazane; Dess-Martin periodane; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene; 3.1: Dess-Martin oxidation;
DOI:10.1021/jo0203140

Reference yield:

: Benzoic acid (E)-(S)-5-methyl-1-((S)-4-methyl-2-oxo-cyclohex-3-enyl)-hex-2-enyl ester

: 472986-73-5
Triethyl-{(1R,6R)-6-[1-((2R,3R)-3-isobutyl-oxiranyl)-vinyl]-3-methyl-cyclohex-2-enyloxy}-silane

Guidance literature:: Multi-step reaction with 5 steps

1.1: CeCl₃*7H₂O; NaBH₄ / methanol / 1 h / -78 - -18 °C

1.2: imidazole / dimethylformamide / 2 h / 0 °C

1.3: diisobutylaluminium hydride / CH₂Cl₂; toluene / 1.5 h / -78 °C

2.1: VO(acac)2; t-BuOOH / CH₂Cl₂; toluene / 2.5 h / 0 °C

3.1: Dess-Martin periodinane / CH₂Cl₂ / 1 h / 0 °C

4.1: tetrahydrofuran; diethyl ether / 1 h / 0 °C

5.1: potassium hexamethyldisilazide / tetrahydrofuran; toluene / 1.5 h / 0 °C

With tert.-butylhydroperoxide; sodium tetrahydroborate; cerium(III) chloride; bis(acetylacetonate)oxovanadium; potassium hexamethylsilazane; Dess-Martin periodane; In tetrahydrofuran; methanol; diethyl ether; dichloromethane; toluene; 3.1: Dess-Martin oxidation;
DOI:10.1021/jo0203140