3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.1^5,9.1^10,13.1^15,18.1^19,23.1^24,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione

Base Information

• Chemical Name: 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.1^5,9.1^10,13.1^15,18.1^19,23.1^24,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione
• CAS No.: 137389-54-9
• Molecular Formula: C₄₄H₃₆N₈O₂
• Molecular Weight: 708.822
• Mol file: 137389-54-9.mol

Synonyms:3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.1^5,9.1^10,13.1^15,18.1^19,23.1^24,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione

Chemical Property of 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.1^5,9.1^10,13.1^15,18.1^19,23.1^24,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.1^5,9.1^10,13.1^15,18.1^19,23.1^24,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione

There total 9 articles about 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.1^5,9.1^10,13.1^15,18.1^19,23.1^24,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 7.0%

1,3-di(aminomethyl)benzene (1477-55-0) + 1,3-bis<1-benzyl-5-methyl-4-((2-hydroxyimino)-1,3-dioxobutyl)-imidazol-2-yl>benzene (137389-52-7) → 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.15,9.110,13.115,18.119,23.124,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione (137389-54-9) + C88H72N16O4 (138286-16-5)

Guidance literature:

With pyridine; calcium chloride; at 105 ℃; for 67h; other conditions; other metal salts; other dilution conditions;

DOI:10.1021/jo00030a038

Reference yield: 4.0%

1,3-di(aminomethyl)benzene (1477-55-0) + 1,3-bis<1-benzyl-5-methyl-4-((2-hydroxyimino)-1,3-dioxobutyl)-imidazol-2-yl>benzene (137389-52-7) → 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.15,9.110,13.115,18.119,23.124,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione (137389-54-9)

Guidance literature:

In sulfolane; at 135 ℃; for 36h;

DOI:10.1016/S0040-4039(00)92699-6

Reference yield: 2.5%

1,3-di(aminomethyl)benzene (1477-55-0) + 1,3-bis<1-benzyl-5-methyl-4-((2-hydroxyimino)-1,3-dioxobutyl)-imidazol-2-yl>benzene (137389-52-7) → 3,11-Dibenzyl-2,12,16,26-tetramethyl-3,11,17,25,29,31,32,34-octaazaheptacyclo<24.2.1.15,9.110,13.115,18.119,23.124,27>octacosa-1,4(29),5(30),6,8,10(31),12,15,17,19,21,23(33),24,26-tetradecaene-14,28-dione (137389-54-9) + C88H72N16O4 (138286-16-5) + 26-acetyl-3,11-dibenzyl-2,12,16-trimethyl-3,11,17,25,28,30,31,33-octaazaheptacyclo<23.2.1.15,9.110,13.115,18.119,23.124,27>tritriaconta-1,4(28),5(29),6,8,10(30),12,15,17,19,21,23(32),24,26-tetradecaen-14-one (138286-14-3) + 15,25-diacetyl-3,11-dibenzyl-2,12-dimethyl-3,11,16,24,27,29,30,32-octaazaheptacyclo<22.2.1.15,9.110,13.114,17.118,22.123,26>dotriaconta-1,4(27),5(28),6,8,10(29),12,14,16,18,20,22(31),23,25-tetradecaene (138286-15-4)

Guidance literature:

With pyridine; at 105 ℃; for 67h;

DOI:10.1021/jo00030a038

upstream raw materials:

1,3-di(aminomethyl)benzene

1,3-bis<1-benzyl-5-methyl-4-((2-hydroxyimino)-1,3-dioxobutyl)-imidazol-2-yl>benzene

1-{2-[3-(4-Acetyl-5-methyl-1H-imidazol-2-yl)-phenyl]-5-methyl-1H-imidazol-4-yl}-ethanone

1-{2-[3-(4-Acetyl-1-benzyl-5-methyl-1H-imidazol-2-yl)-phenyl]-1-benzyl-5-methyl-1H-imidazol-4-yl}-ethanone

Downstream raw materials:

C₅₈H₄₈N₈O₂

C₅₈H₄₈N₈O₂