Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Base Information

Chemical Name:Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester
CAS No.:81566-13-4
Molecular Formula:C₁₄H₂₂O₄
Molecular Weight:254.326
Hs Code.:

Synonyms:Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

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Chemical Property of Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

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Technology Process of Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

There total 14 articles about Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

: 81566-15-6,91383-50-5
Acetic acid (3S,5S)-5-hydroxymethyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

: 81566-13-4
Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Guidance literature:: With pyridinium chlorochromate; In dichloromethane; for 2h; Ambient temperature;
DOI:10.1248/cpb.32.1294

Reference yield: 97.0%

: 108-24-7
acetic anhydride

: 81566-14-5
(1S,5S)-3-Hydroxymethyl-5-methoxy-2,2,4-trimethyl-cyclohex-3-enecarbaldehyde

: 81566-13-4
Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Guidance literature:: In pyridine; for 5h; Ambient temperature;
DOI:10.1248/cpb.32.1294

Reference yield:

: 73616-73-6,76231-57-7
Acetic acid (1S,4S)-4-bromomethyl-2,2-dimethyl-3-methylene-cyclohexylmethyl ester

: 81566-13-4
Acetic acid (3S,5S)-5-formyl-3-methoxy-2,6,6-trimethyl-cyclohex-1-enylmethyl ester

Guidance literature:: Multi-step reaction with 10 steps

1: 2.11 g / 10 percent KOH / methanol / 1.5 h / Ambient temperature

2: 97 percent / p-toluenesulfonic acid monohydrate / CH₂Cl₂ / 0.5 h

3: 42 percent / 80 percent m-chloroperbenzoic acid / CH₂Cl₂ / 1 h / Ambient temperature

4: 82 percent / sodium tertiary amylate / tetrahydrofuran; dimethylsulfoxide / 0.05 h / 70 °C

5: 92 percent / Na, liq. NH₃ / tetrahydrofuran / 0.5 h / -78 °C

6: 635 mg / pyridine / Ambient temperature

7: 92 percent / selenium dioxide / dioxane; pyridine / 2.5 h / 80 °C

8: 95 percent / silver oxide / dimethylformamide / 24 h / Ambient temperature

9: 96 percent / p-toluenesulfonic acid monohydrate / aq. ethanol / 1.5 h / Ambient temperature

10: 100 percent / pyridinium chlorochromate / CH₂Cl₂ / 2 h / Ambient temperature

With potassium hydroxide; selenium(IV) oxide; ammonia; sodium; sodium tert-pentoxide; toluene-4-sulfonic acid; 3-chloro-benzenecarboperoxoic acid; pyridinium chlorochromate; silver(l) oxide; In tetrahydrofuran; 1,4-dioxane; pyridine; methanol; ethanol; dichloromethane; dimethyl sulfoxide; N,N-dimethyl-formamide;
DOI:10.1248/cpb.32.1294